Relaxor ferroelectric-like behavior in 10PbTiO3-10Fe2O3-30V2O5-50B2O3 glass for energy storage applications

被引：6
作者：
El-Desoky, M. M. [1 ,2 ]
Wally, N. K. [1 ]
Ali, A. M. [1 ]
Harby, Amany E. [1 ]
Hannora, Ahmed E. [3 ]
机构：
[1] Suez Univ, Fac Sci, Dept Phys, Suez 43518, Egypt
[2] Acad Sci Res & Technol ASRT Arab Republ Egypt, Cairo, Egypt
[3] Suez Univ, Fac Petr & Min Engn, Dept Sci & Engn Math, Suez 43518, Egypt
来源：
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS | 2021年 / 32卷 / 17期
关键词：
DIELECTRIC-PROPERTIES; RAMAN-SCATTERING; TEMPERATURE;
D O I：
10.1007/s10854-021-06727-3
中图分类号：
TM [电工技术]; TN [电子技术、通信技术];
学科分类号：
0808 ; 0809 ;
摘要：
Recently, demand increased for dielectric materials used in energy storage devices at high voltage applications. Appearance of polar clusters in glass matrix could promote its use in energy storage applications. Conventional quenched glass sample of composition 10PbTiO(3)-10Fe(2)O(3)-30V(2)O(5)-50B(2)O(3) were successfully developed. The glassy nature was confirmed by XRD and DSC measurements. Boson peak observed at low frequency from the Raman spectra confirms polar cluster formation. Dielectric properties of prepared glass were investigated in a wide range of frequency and temperature. Broad and diffuse peak of dielectric permittivity shifted to the higher temperatures, denoting the typical relaxor ferroelectrics like behavior. Sample shows energy storage density of about 164.7 mJ/cm(3) at room temperature. Quenched glass sample shows typical anti-ferromagnetic behavior.
引用
收藏
页码：22408 / 22416
页数：9
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