Synthesis of cyclopentadiene derivatives by retro-Diels-Alder reaction of norbornadiene derivatives

被引：31
作者：
Dalkilic, Erdin [1 ]
Dastan, Arif [1 ]
机构：
[1] Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey
来源：
TETRAHEDRON | 2015年 / 71卷 / 13期
关键词：
Cyclopentadiene; Cyclopentadiene derivatives; retro-Diels-Alder; Tetrazine; Norbornadiene; SUBSTITUTED CYCLOPENTADIENES; TETRASUBSTITUTED CYCLOPENTADIENES; EFFICIENT SYNTHESIS; COMPLEXES; KETONES; ALKYNES; ZIRCONACYCLOPENTADIENES; DIENOPHILES; CYCLIZATION; GENERATION;
D O I：
10.1016/j.tet.2015.02.023
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Synthesis of cyclopentadiene derivatives starting from norbornadiene was investigated using dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate. The products obtained were either cyclopentadienes or diazines depending on the substituents. The driving force for the formation of these products was discussed in terms of electronic effects. (C) 2015 Elsevier Ltd. All rights reserved.
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页码：1966 / 1970
页数：5
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