Morphologic and crystallographic studies on electrochemically formed chromium nitride films

被引：1
作者：
Amezawa, Koji
Goto, Takuya
Tsujimura, Hiroyuki
Uchimoto, Yoshiharu
Hagiwara, Rika
Tomii, Yoichi
Ito, Yasuhiko
机构：
[1] Tohoku Univ, Grad Sch Environm Studies, Aoba Ku, Sendai, Miyagi 9808579, Japan
[2] Kyoto Univ, Grad Sch Energy Sci, Sakyo Ku, Kyoto 6068501, Japan
[3] Kyoto Univ, Grad Sch Human & Environm Studies, Sakyo Ku, Kyoto 6068501, Japan
[4] Doshisya Univ, Fac Engn, Dept Environm Syst Sci, Kyotanabe, Kyoto 6100321, Japan
来源：
ELECTROCHIMICA ACTA | 2007年 / 53卷 / 01期
关键词：
chromium nitride; electrochemical nitriding; molten salt; nitride film; morphology;
D O I：
10.1016/j.electacta.2007.06.013
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Chromium nitride films were prepared by anodically oxidizing nitride ions at 0.4-1.5 V versus Li+/Li on chromium substrates in molten LiCl-KCI-Li3N systems at 723 K. A crystalline Cr2N film was successfully prepared at 0.4-4.4 V, and was thicker at more positive electrolytic potential. At 1.5 V, a Cr-N film could be also obtained, but its growth rate was relatively low. The film prepared at 1.5 V consisted of two distinctive layers. The surface layer was amorphous Cr-N containing crystalline CrN particles, and the inner layer was crystalline CrN. It was considered the existence of the amorphous phase suppressed the film growth. (C) 2007 Elsevier Ltd. All rights reserved.
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页码：122 / 126
页数：5
相关论文
共 14 条
[1]   THE SINGLE-ELECTRODE PELTIER HEATS OF LI-AL ALLOY ELECTRODES IN LICL-KCL EUTECTIC SYSTEM [J].
AMEZAWA, K ;
ITO, Y ;
TOMII, Y .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (11) :3096-3103
[2]   Thermodynamic properties and single-electrode Peltier heats of a Li-Al alloy in a LiCl-KCl eutectic melt [J].
Amezawa, K ;
Yamamoto, N ;
Tomii, Y ;
Ito, Y .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (03) :1069-1074
[3]   Electrochemical formation of iron nitride film in a molten LiCl-KCl-Li3N system [J].
Goto, T ;
Obata, R ;
Ito, Y .
ELECTROCHIMICA ACTA, 2000, 45 (20) :3367-3373
[4]   Electrochemical behavior of nitride ions in a molten chloride system [J].
Goto, T ;
Tada, M ;
Ito, Y .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (07) :2271-2276
[5]   ELECTROCHEMICAL SURFACE NITRIDING OF TITANIUM IN MOLTEN-SALT SYSTEM [J].
GOTO, T ;
TADA, M ;
ITO, Y .
ELECTROCHIMICA ACTA, 1994, 39 (8-9) :1107-1113
[6]   Electrochemical nitriding of Sn in LiCl-KCl-Li3N systems [J].
Goto, T ;
Ito, Y .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2005, 66 (2-4) :418-421
[7]   Electrochemical formation of AlN in molten LiCl-KCI-Li3N systems [J].
Goto, T ;
Iwaki, T ;
Ito, Y .
ELECTROCHIMICA ACTA, 2005, 50 (06) :1283-1288
[8]   Electrochemical surface nitriding of zirconium in LiCl-KCl-Li3N systems [J].
Goto, T ;
Ishigaki, H ;
Ito, Y .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2004, 371 (1-2) :353-358
[9]   Non-conventional electrolytes for electrochemical applications [J].
Ito, Y ;
Nohira, T .
ELECTROCHIMICA ACTA, 2000, 45 (15-16) :2611-2622
[10]   Corrosion properties of active screen plasma nitrided 316 austenitic stainless steel [J].
Li, CX ;
Bell, T .
CORROSION SCIENCE, 2004, 46 (06) :1527-1547
12