Sequential palladium-catalyzed coupling reactions on solid-phase

被引：25

作者：

Doi, Takayuki ^{[1
]}

Inoue, Hitoshi ^{[1
]}

Tokita, Masatoshi ^{[2
]}

Watanabe, Junji ^{[2
]}

Takahashi, Takashi ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Appl Chem, 2-12-1 Ookayama, Tokyo 1528552, Japan

[2] Tokyo Inst Technol, Dept Organ & Polymer Mat, Tokyo 1528552, Japan

来源：

JOURNAL OF COMBINATORIAL CHEMISTRY | 2008年 / 10卷 / 01期

关键词：

D O I：

10.1021/cc7000925

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Six-types of palladium-catalyzed coupling, Mizoroki-Heck, Migita-Stille, Sonogashira, carbonylative esterification, carbonylative Stille, and carbonylative Sonogashira reactions, were performed on a polymer support. The above coupling reactions of m- and p-substituted aromatic rings, followed by carbonylative esterification with m- and p-substituted anisol derivatives were carried out in a combinatorial manner. Acid cleavage from the polymer-support provided the conjugated aromatic ring systems I and 2, which are the core parts of rodlike liquid crystals.

引用

页码：135 / 141

页数：7

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