Branched Polymer Materials as Proton Exchange Membranes for Fuel Cell Applications

被引：41
作者：
Neelakandan, Sivasubramaniyan [1 ]
Wang, Li [1 ]
Zhang, Boping [1 ]
Ni, Jiangpeng [1 ]
Hu, Meishao [1 ]
Gao, Chunmei [2 ]
Wong, Wai-Yeung [1 ,3 ]
Wang, Lei [1 ]
机构：
[1] Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen Key Lab Polymer Sci & Technol, Shenzhen 518060, Guangdong, Peoples R China
[2] Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen, Guangdong, Peoples R China
[3] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Peoples R China
来源：
POLYMER REVIEWS | 2022年 / 62卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Branched polymer; proton exchange membrane; polyarylene ether; polyimide; polybenzimidazole; fuel cell; POLY(ETHER ETHER KETONE)S; SULFONIC-ACID GROUPS; CONDUCTIVE POLYIMIDE ELECTROLYTES; CROSS-LINKED POLYBENZIMIDAZOLE; ALKYLSULFONATED SIDE-CHAINS; POLY(ARYLENE ETHER)S; COMPOSITE MEMBRANES; HYPERBRANCHED POLYBENZIMIDAZOLES; METHANOL RESISTANCE; GRAPHENE OXIDE;
D O I：
10.1080/15583724.2021.1964524
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Recent progress on branched polymer membranes as electrolyte materials for proton exchange membrane fuel cell (PEMFC) applications has attracted interest due to the limitations of commercially available Nafion (R) membranes. Branched polymer membranes have shown improved chemical stability, proton conductivity, and good solubility. The branching degree and the structure of the branching agent have an essential correlation with the characteristics of the polymer membranes. This review presents the most recent and promising design strategies and characteristics of branched polymers as proton exchange membranes for both low- and high-temperature proton exchange membrane fuel cells. Recent advances in branched polymers are summarized, including branched sulfonated poly(aryl ether)s, branched sulfonated polyimides, branched polybenzimidazoles, etc. The remaining challenges and prospects in proton exchange membranes are also discussed.
引用
收藏
页码：261 / 295
页数：35
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