Branched Polymer Materials as Proton Exchange Membranes for Fuel Cell Applications

被引：41
作者：
Neelakandan, Sivasubramaniyan [1 ]
Wang, Li [1 ]
Zhang, Boping [1 ]
Ni, Jiangpeng [1 ]
Hu, Meishao [1 ]
Gao, Chunmei [2 ]
Wong, Wai-Yeung [1 ,3 ]
Wang, Lei [1 ]
机构：
[1] Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen Key Lab Polymer Sci & Technol, Shenzhen 518060, Guangdong, Peoples R China
[2] Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen, Guangdong, Peoples R China
[3] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Peoples R China
来源：
POLYMER REVIEWS | 2022年 / 62卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Branched polymer; proton exchange membrane; polyarylene ether; polyimide; polybenzimidazole; fuel cell; POLY(ETHER ETHER KETONE)S; SULFONIC-ACID GROUPS; CONDUCTIVE POLYIMIDE ELECTROLYTES; CROSS-LINKED POLYBENZIMIDAZOLE; ALKYLSULFONATED SIDE-CHAINS; POLY(ARYLENE ETHER)S; COMPOSITE MEMBRANES; HYPERBRANCHED POLYBENZIMIDAZOLES; METHANOL RESISTANCE; GRAPHENE OXIDE;
D O I：
10.1080/15583724.2021.1964524
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Recent progress on branched polymer membranes as electrolyte materials for proton exchange membrane fuel cell (PEMFC) applications has attracted interest due to the limitations of commercially available Nafion (R) membranes. Branched polymer membranes have shown improved chemical stability, proton conductivity, and good solubility. The branching degree and the structure of the branching agent have an essential correlation with the characteristics of the polymer membranes. This review presents the most recent and promising design strategies and characteristics of branched polymers as proton exchange membranes for both low- and high-temperature proton exchange membrane fuel cells. Recent advances in branched polymers are summarized, including branched sulfonated poly(aryl ether)s, branched sulfonated polyimides, branched polybenzimidazoles, etc. The remaining challenges and prospects in proton exchange membranes are also discussed.
引用
收藏
页码：261 / 295
页数：35
相关论文
共 108 条
  • [1] Comparative study of sulfonated branched and linear poly(phenylene)s polymer electrolyte membranes for fuel cells
    Ahmed, Faiz
    Sutradhar, Sabuj Chandra
    Ryu, Taewook
    Jang, Hohyoun
    Choi, Kunyoung
    Yang, Hanmo
    Yoon, Sujin
    Rahman, Md. Mahbubur
    Kim, Whangi
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (10) : 5374 - 5385
  • [2] Aliphatic/aromatic polyimide lonomers as a proton conductive membrane for fuel cell applications
    Asano, N
    Aoki, M
    Suzuki, S
    Miyatake, K
    Uchida, H
    Watanabe, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (05) : 1762 - 1769
  • [3] Hydrolytically stable polyimide ionomer for fuel cell applications
    Asano, N
    Miyatake, K
    Watanabe, M
    [J]. CHEMISTRY OF MATERIALS, 2004, 16 (15) : 2841 - 2843
  • [4] Effect of the Hydrophobic Component on the Properties of Sulfonated Poly(arylene ether sulfone)s
    Bae, Byungchan
    Miyatake, Kenji
    Watanabe, Masahiro
    [J]. MACROMOLECULES, 2009, 42 (06) : 1873 - 1880
  • [5] New Hyperbranched Polymers for Membranes of High-Temperature Polymer Electrolyte Membrane Fuel Cells: Determination of the Crystal Structure and Free-Volume Size
    Bhadra, Sambhu
    Ranganathaiah, C.
    Kim, Nam Hoon
    Kim, Seong-Il
    Lee, Joong Hee
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 121 (02) : 923 - 929
  • [6] Hyperbranched poly(benzimidazole-co-benzene) with honeycomb structure as a membrane for high-temperature proton-exchange membrane fuel cells
    Bhadra, Sambhu
    Kim, Nam Hoon
    Choi, Ji Sun
    Rhee, Kyong Yop
    Lee, Joong Hee
    [J]. JOURNAL OF POWER SOURCES, 2010, 195 (09) : 2470 - 2477
  • [7] Polymer membranes for high temperature proton exchange membrane fuel cell: Recent advances and challenges
    Bose, Saswata
    Kuila, Tapas
    Thi Xuan Lien Nguyen
    Kim, Nam Hoon
    Lau, Kin-tak
    Lee, Joong Hee
    [J]. PROGRESS IN POLYMER SCIENCE, 2011, 36 (06) : 813 - 843
  • [8] Synthesis and properties of sulfonated polyimides from homologous sulfonated diamines bearing bis(aminophenoxyphenyl)sulfone
    Chen, Shouwen
    Yin, Yan
    Kita, Hidetoshi
    Okamoto, Ken-Ichi
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (13) : 2797 - 2811
  • [9] Branched and cross-linked proton conductive poly(arylene ether sulfone) ionomers: Synthesis and properties
    Chikashige, Yohei
    Chikyu, Yoshiki
    Miyatake, Kenji
    Watanabe, Masahiro
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2006, 207 (15) : 1334 - 1343
  • [10] (Semi-)Interpenetrating polymer networks as fuel cell membranes
    Chikh, Linda
    Delhorbe, Virginie
    Fichet, Odile
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2011, 368 (1-2) : 1 - 17
12345678910