An anionic weak acceptor 2-aminomethylsulfo-3,5,6-trichloro-1, 4-benzoquinone and its BEDT-TTF-based charge-transfer salts

被引：8

作者：

Akutsu, Hiroki ^{[1
]}

Yamada, Jun-ichi

Nakatsuji, Shin'ichi

Turner, Scott S.

机构：

[1] Univ Hyogo, Grad Sch Mat Sci, 3-2-1 Kuoto, Akogun, Hyogo 6781297, Japan

[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

SOLID STATE COMMUNICATIONS | 2007年 / 144卷 / 3-4期

关键词：

organic crystals;

D O I：

10.1016/j.ssc.2007.07.034

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

We have prepared a novel organic anionic weak acceptors 2-aminomethylsulfo-3,5,6-trichloro-1,4-benzoquinone (1), as a PPh4 salt. Cyclic voltammetry indicates that its reduction potential is 0.53 V lower than that of chloranil. Electrocrystallisation with BEDT-TTF cave two salts. beta-beta-(BEDT-TTF)(2)(1)-0.5H(2)O (2) and beta"-(BEDT-TTF)(2)(1).CH3OH (3). Their crystal structures and physical properties are reported. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：144 / 147

页数：4

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