Structural study of holmium(III) and uranium(VI) organic ligand complexes by extended x-ray absorbtion fine-structure spectroscopy

被引：17
|
作者：
Yaita, T [1 ]
Narita, H [1 ]
Suzuki, S [1 ]
Tachimori, S [1 ]
Shiwaku, H [1 ]
Motohashi, H [1 ]
机构：
[1] Japan Atom Energy Res Inst, Dept Chem & Fuel Res, Tokai, Ibaraki 31911, Japan
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 1998年 / 271卷
关键词：
EXAFS; lanthanide; uranium; complex structure in solution; diphosphine dioxide; CMPO; amide;
D O I：
10.1016/S0925-8388(98)00051-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The structures of holmium-organophosphorus mono- and bidentate ligands and uranium-monoamide ligand complexes in solutions were determined by extended X-ray absorption fine-structure spectroscopy. The diphosphine dioxide coordinates directly to holmium with symmetric bidentate mode, while the carbamoyl phosphine oxide with asymmetric bidentate mode. The structure for uranium-N,N-dihexyl-3-ethylhexanamide complex is very similar to that for the aqua nitrate uranyl complex in bond distance and coordination number. (C) 1998 Elsevier Science S.A.
引用
收藏
页码：184 / 188
页数：5
相关论文
共 50 条
  • [1] Local structure of NiAl compounds investigated by extended X-ray absorption fine-structure spectroscopy
    Tian, J. S.
    Han, G. M.
    Wei, H.
    Jin, T.
    Dargusch, M. S.
    JOURNAL OF SYNCHROTRON RADIATION, 2012, 19 : 503 - 507
  • [2] Characterization of extraction complexes of Am(III) with dialkyldithiophosphinic acids by extended X-ray absorption fine structure spectroscopy
    Tian, GX
    Zhu, YJ
    Xu, JM
    Hu, TD
    Xie, YN
    JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 334 (1-2) : 86 - 91
  • [3] X-ray absorption fine structure spectroscopic study of uranium nitrides
    Frederic Poineau
    Charles B. Yeamans
    G. W. C. Silva
    Gary S. Cerefice
    Alfred P. Sattelberger
    Kenneth R. Czerwinski
    Journal of Radioanalytical and Nuclear Chemistry, 2012, 292 : 989 - 994
  • [4] X-ray absorption fine structure spectroscopic study of uranium nitrides
    Poineau, Frederic
    Yeamans, Charles B.
    Silva, G. W. C.
    Cerefice, Gary S.
    Sattelberger, Alfred P.
    Czerwinski, Kenneth R.
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2012, 292 (03) : 989 - 994
  • [5] STRUCTURAL STUDIES ON NEW CO POLYAMINE COMPLEXES BY X-RAY-ABSORPTION FINE-STRUCTURE SPECTROSCOPY
    AKAI, T
    OKUDA, M
    HORIUCHI, K
    MATSUURA, J
    KOIKE, Y
    YIMAGAWA, M
    FUJIKAWA, T
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1994, 33 (11): : 6360 - 6367
  • [6] Crystal chemistry of iron in natural grandidierites: an X-ray absorption fine-structure spectroscopy study
    Farges, F
    PHYSICS AND CHEMISTRY OF MINERALS, 2001, 28 (09) : 619 - 629
  • [7] Crystal chemistry of iron in natural grandidierites: an X-ray absorption fine-structure spectroscopy study
    F. Farges
    Physics and Chemistry of Minerals, 2001, 28 : 619 - 629
  • [8] X-ray diffraction and extended X-ray absorption fine-structure study of RMn(2) hydrides (R=Y, Gd or Dy)
    Przewoznik, J
    PaulBoncour, V
    Latroche, M
    PercheronGuegan, A
    JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 232 (1-2) : 107 - 118
  • [9] EXTENDED X-RAY-ABSORPTION FINE-STRUCTURE STUDY OF ZNSSE AND ZNMGSSE
    MARUYAMA, T
    OGAWA, T
    AKIMOTO, K
    KITAJIMA, Y
    ITO, S
    ISHIBASHI, A
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1995, 34 (5A): : L539 - L542
  • [10] Local structure investigation of Co-Fe-Si-B ribbons by extended X-ray absorption fine-structure spectroscopy
    Deshmukh, A. A.
    Srivastava, A. P.
    Singh, J. P.
    Kumar, Manish
    Chae, K. H.
    Asokan, K.
    Palikundwar, U. A.
    JOURNAL OF SYNCHROTRON RADIATION, 2021, 28 : 240 - 246
12345