Improved field emission properties of thiolated multi-wall carbon nanotubes on a flexible carbon cloth substrate

被引:44
作者
Chuang, F. T. [1 ]
Chen, P. Y.
Cheng, T. C.
Chien, C. H.
Li, B. J.
机构
[1] Natl Chiao Tung Univ, Dept Mat Sci & Engn, Hsinchu 30050, Taiwan
[2] Natl Nano Device Labs, Hsinchu 30078, Taiwan
[3] Natl Chiao Tung Univ, Dept Elect Engn, Hsinchu 30050, Taiwan
[4] Natl Chiao Tung Univ, ITRI, Hsinchu 30050, Taiwan
关键词
D O I
10.1088/0957-4484/18/39/395702
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this paper we report the observation of enhanced field emission properties from thiolated multi-wall carbon nanotubes ( MWCNTs) produced by a simple and effective two- step chemical surface modification technique. This technique implements carboxylation and thiolation on the MWCNTs synthesized by microwave plasma chemical vapor deposition ( MPCVD) on the flexible carbon cloth substrate. The resulting thiolated MWCNTs were found to have a very low threshold field value of 1.25 V mu m(-1) and a rather high field enhancement factor of 1.93 x 10(4), which are crucial for applications in versatile vacuum microelectronics.
引用
收藏
页数:5
相关论文
共 26 条
[1]   Enhanced field emission of ZnO nanowires [J].
Banerjee, D ;
Jo, SH ;
Ren, ZF .
ADVANCED MATERIALS, 2004, 16 (22) :2028-+
[2]   Field emission from carbon nanotubes:: the first five years [J].
Bonard, JM ;
Kind, H ;
Stöckli, T ;
Nilsson, LA .
SOLID-STATE ELECTRONICS, 2001, 45 (06) :893-914
[3]   Growth and characteristics of carbon nanotubes on carbon cloth as electrodes [J].
Chen, CC ;
Chen, CF ;
Hsu, CH ;
Li, IH .
DIAMOND AND RELATED MATERIALS, 2005, 14 (3-7) :770-773
[4]   Microwave digestion and acidic treatment procedures for the purification of multi-walled carbon nanotubes [J].
Chen, CM ;
Chen, M ;
Peng, YW ;
Lin, CH ;
Chang, LW ;
Chen, CF .
DIAMOND AND RELATED MATERIALS, 2005, 14 (3-7) :798-803
[5]   Fully sealed, high-brightness carbon-nanotube field-emission display [J].
Choi, WB ;
Chung, DS ;
Kang, JH ;
Kim, HY ;
Jin, YW ;
Han, IT ;
Lee, YH ;
Jung, JE ;
Lee, NS ;
Park, GS ;
Kim, JM .
APPLIED PHYSICS LETTERS, 1999, 75 (20) :3129-3131
[6]   Self-oriented regular arrays of carbon nanotubes and their field emission properties [J].
Fan, SS ;
Chapline, MG ;
Franklin, NR ;
Tombler, TW ;
Cassell, AM ;
Dai, HJ .
SCIENCE, 1999, 283 (5401) :512-514
[7]  
Gangloff L, 2004, NANO LETT, V4, P1575, DOI 10.1021/nl049401t
[8]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[9]   Field emission of carbon nanotubes grown on carbon cloth [J].
Jo, SH ;
Wang, DZ ;
Huang, JY ;
Li, WZ ;
Kempa, K ;
Ren, ZF .
APPLIED PHYSICS LETTERS, 2004, 85 (05) :810-812
[10]   Surface thiolation of carbon nanotubes as supports: A promising route for the high dispersion of Pt nanoparticles for electrocatalysts [J].
Kim, YT ;
Mitani, T .
JOURNAL OF CATALYSIS, 2006, 238 (02) :394-401