Superstatistics of Diatomic Molecules with the Shifted Deng-Fan Potential Model

被引:10
作者
Edet, Collins [1 ]
Ikot, Akpan [1 ]
机构
[1] Univ Port Harcourt, Dept Phys, Theoret Phys Grp, Port Harcourt, Nigeria
关键词
shifted Deng-Fan potential; diatomic molecules; superstatistics; L-STATE SOLUTIONS; SCHRODINGER-EQUATION; THERMODYNAMIC PROPERTIES; THERMAL-PROPERTIES; MORSE; MECHANICS; STATISTICS;
D O I
10.33263/BRIAC123.41264139
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this article, we discuss the thermodynamic properties of the shifted Deng-Fan potential for HCl, CrH, CuLi, and ScF diatomic molecules using the q-deformed superstatistics approach. The partition function is obtained with the help of the generalized Boltzmann factor from the modified Dirac delta distribution. In addition, thermodynamic functions such as entropy, specific heat capacity, free energy, and mean energy are obtained using the partition function. Our results are presented graphically, and the ordinary statistical quantities are recovered when the deformation parameter tends to zero. Our results may be useful in the study of thermal fluctuations in atomic and molecular systems involving short-range interactions.
引用
收藏
页码:4126 / 4139
页数:14
相关论文
共 64 条
[1]  
[Anonymous], 1991, THERMODYNAMICS STAT
[2]  
[Anonymous], 1964, Handbook of mathematical functions with formulas, graphs, and mathematical tables. Applied mathematics series
[3]   MODIFIED SHIFTED LARGE-N APPROACH TO THE MORSE OSCILLATOR [J].
BAG, M ;
PANJA, MM ;
DUTT, R ;
VARSHNI, YP .
PHYSICAL REVIEW A, 1992, 46 (09) :6059-6062
[4]   Superstatistical generalization of the work fluctuation theorem [J].
Beck, C ;
Cohen, EGD .
PHYSICA A-STATISTICAL MECHANICS AND ITS APPLICATIONS, 2004, 344 (3-4) :393-402
[5]   Superstatistics: theory and applications [J].
Beck, C .
CONTINUUM MECHANICS AND THERMODYNAMICS, 2004, 16 (03) :293-304
[6]   Generalized statistical mechanics of cosmic rays [J].
Beck, C .
PHYSICA A-STATISTICAL MECHANICS AND ITS APPLICATIONS, 2004, 331 (1-2) :173-181
[7]   Lagrangian acceleration statistics in turbulent flows [J].
Beck, C .
EUROPHYSICS LETTERS, 2003, 64 (02) :151-157
[8]   Superstatistics [J].
Beck, C ;
Cohen, EGD .
PHYSICA A-STATISTICAL MECHANICS AND ITS APPLICATIONS, 2003, 322 (1-4) :267-275
[9]   Any l-state solutions of the Morse potential through the Pekeris approximation and Nikiforov-Uvarov method [J].
Berkdemir, C ;
Han, HG .
CHEMICAL PHYSICS LETTERS, 2005, 409 (4-6) :203-207
[10]   Bound state solutions of the Klein-Gordon equation with the generalized Poschl-Teller potential [J].
Chen, Tao ;
Diao, Yong-Feng ;
Jia, Chun-Sheng .
PHYSICA SCRIPTA, 2009, 79 (06)