X-ray diffraction data for the new ferroelectric tetragonal tungsten bronze phases, Ba2RETi2M3O15:: M=Nb and RE=La, Pr, Nd, Sm, Gd, Dy, (Bi); M=Ta and RE=La, Nd

被引:10
作者
Miles, GC [1 ]
Stennett, MC [1 ]
Pickthall, D [1 ]
Kirk, CA [1 ]
Reaney, IM [1 ]
West, AR [1 ]
机构
[1] Univ Sheffield, Dept Mat Engn, Sheffield S1 3JD, S Yorkshire, England
关键词
D O I
10.1154/1.1803838
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
X-ray powder diffraction data are presented for nine new phases with the tetragonal tungsten bronze structure. By comparison with the structure of the M = Nb,RE = La analogue, these contain Ba in the large pentagonal sites with coordination number 15, a range of large rare-earth cations and Bi in the twelve coordinate sites, and the smaller cations, Ti and either Nb or Ta, in the octahedral framework sites. The a lattice parameter data of the tetragonal unit cell show an approximately linear variation with trivalent ion radius, apart from Dy, whose value appears to be anomalous; data for c show little variation with trivalent ion radius. (c) 2005 International Centre for Diffraction Data.
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页码:43 / 46
页数:4
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