Synthesis, Crystal Structure and Magnetic Property of 2D Coordination Polymer {[Cu2(BIPA)2(bpe)2]•H2O}n

被引：0

作者：

Wang Tao ^{[1
]}

Liu Guang-Xiang ^{[1
,2
]}

Wang Yan ^{[1
,2
]}

Ren Xiao-Ming ^{[1
]}

机构：

[1] Anqing Normal Univ, Sch Chem & Chem Engn, Anhui Key Lab Funct Coordinat Cpds, Anqing 246003, Anhui, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 27卷 / 04期

关键词：

Cu(II) complex; 5-bromoisophthalic acid; crystal structure; magnetism; METAL-ORGANIC FRAMEWORK; COPPER(II) COMPLEXES; SOLVENT; TEREPHTHALATE; COBALT(II); BRIDGES;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 2D coordination polymer of {[Cu-2(BIPA)(2)(bpe)(2)]center dot H2O}(n) (1) (H(2)BIPA=5-bromoisophthalic acid and bpe=1,2-bis(4-pyridyl)ethane) has been prepared and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The crystal is of triclinic, space group P (1) over bar with a=0.951 2(1) nm, b=1.011 5(1) nm, c=1.170 8(2) nm, alpha=75.042(2)degrees, beta=76.605(3)degrees, gamma=70.640(2)degrees, V=1.013 5(3) nm(3), D-c=1.638 g.cm(-3), Z=1, F(000)= 500, Goof=1.022, R-1=0.052 7, wR(2)=0.114 9. Complex 1 consists of one-dimensional [Cu(BIPA)](n) chains that are further bridged by trans-bpe into a two-dimensional layer structure. Magnetic data for 1 show a weak antiferromagnetic interaction between the two Cu(II) ions with J=-1.54 cm(-1). CCDC: 785745.

引用

页码：771 / 775

页数：5

共 30 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].

ADDISON, AW ;

RAO, TN ;

REEDIJK, J ;

VANRIJN, J ;

VERSCHOOR, GC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356

[2]

[Anonymous], 2002, SAINT VERS 6 02A

[3] Structure and magnetism of coordination polymers containing dicyanamide and tricyanomethanide [J].

Batten, SR ;

Murray, KS .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :103-130

[4] Polycatenation, polythreading and polyknotting in coordination network chemistry [J].

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :247-289

[5] Copper(II) and cobalt(II) coordination polymers with bridging 1,2,4,5-benzenetetracarboxylate and N-methylimidazole:: coordination number-determined sheet topology [J].

Cheng, DP ;

Khan, MA ;

Houser, RP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (24) :4555-4560

[6] Ferromagnetic and antiferromagnetic polymeric complexes with the macrocyclic ligand 1,4,7-triazacyclononane [J].

Cheng, P ;

Yan, SP ;

Xie, CZ ;

Zhao, B ;

Chen, XY ;

Liu, XW ;

Li, CH ;

Liao, DZ ;

Jiang, ZH ;

Wang, GL .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (11) :2369-2378

[7] Helical-chain copper(II) complexes and a cyclic tetranuclear copper(II) complex with single syn-anti carboxylate bridges and ferromagnetic exchange interactions [J].

Colacio, E ;

Ghazi, M ;

Kivekäs, R ;

Moreno, JM .

INORGANIC CHEMISTRY, 2000, 39 (13) :2882-2890

[8] Dimer complexes of 2,4-toluenediamine-N,N,N',N'-tetraacetic acid (2,4-TDTA) with copper(II), nickel(II), cobalt(II), zinc(II) and manganese(II). Studies in aqueous solution and solid state. X-ray crystal structures of Na-4[Ni-2(2,4-TDTA)(2)]center dot 15H(2)O and Na-4[Cu-2(2,4-TDTA)(2)]center dot 20H(2)O [J].

Dominguez, S ;

Mederos, A ;

Gili, P ;

Rancel, A ;

RIvero, AE ;

Brito, F ;

Lloret, F ;

Solans, X ;

RuizPerez, C ;

Rodriguez, ML ;

Brito, I .

INORGANICA CHIMICA ACTA, 1997, 255 (02) :367-380

[9] Synthesis and hydrogen sorption properties of carborane based metal-organic framework materials [J].

Farha, Omar K. ;

Spokoyny, Alexander M. ;

Mulfort, Karen L. ;

Hawthorne, M. Frederick ;

Mirkin, Chad A. ;

Hupp, Joseph T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (42) :12680-+

[10] The role of temperature in the synthesis of hybrid inorganic-organic materials:: the example of cobalt succinates [J].

Forster, PM ;

Burbank, AR ;

Livage, C ;

Férey, G ;

Cheetham, AK .

CHEMICAL COMMUNICATIONS, 2004, (04) :368-369

← 1 2 3 →