Highly enantioselective synthesis of cyclic sulfamidates and sulfamides via rhodium-catalyzed transfer hydrogenation

被引:30
|
作者
Lee, Sun Ah [1 ]
Kwak, Se Hun [2 ]
Lee, Kee-In [1 ,2 ]
机构
[1] Korea Res Inst Chem Technol, Green Chem Div, Taejon 305600, South Korea
[2] Univ Sci & Technol, Taejon 305333, South Korea
关键词
ASYMMETRIC TRANSFER HYDROGENATION; INTRAMOLECULAR DIAMINATION; ALLYLIC SUBSTITUTION; CONJUGATED DIENES; COMPLEXES; IMINES; DERIVATIVES; FACILE; AMINES; LIGAND;
D O I
10.1039/c0cc04166a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We achieved highly enantioselective synthesis of cyclic 1,2-sulfamidates and -sulfamides via rhodium-catalyzed transfer hydrogenation, and also revealed one-pot preparation of cyclic N-sulfonylimines from alpha-hydroxy ketones.
引用
收藏
页码:2372 / 2374
页数:3
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