trans-Bis(isopuinoline-3-carboxylato-κ2N,O)bis(methanol-κO)iron(II)

被引:1
作者
Okabe, N [1 ]
Muranishi, Y [1 ]
机构
[1] Kinki Univ, Fac Pharmaceut Sci, Osaka 5778502, Japan
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷
关键词
D O I
10.1107/S160053680301972X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title complex, [Fe(C10H6NO2)(2)(CH4O)(2)], contains an Fe-II ion at a center of inversion. The Felt ion has a distorted octahedral coordination geometry, and is coordinated by two bidentate isoquinoline-3-carboxylate ligands through N and O atoms, and by two methanol O atoms. The two isoquinoline-3-carboxylate ligands lie in a trans position with respect to one another in the equatorial plane, and the two methanol ligands occupy the axial positions. The complex molecules are linked together by hydrogen bonds between the methanol ligands and the carboxylate groups.
引用
收藏
页码:M897 / M899
页数:3
相关论文
共 16 条
[1]   SIR97:: a new tool for crystal structure determination and refinement [J].
Altomare, A ;
Burla, MC ;
Camalli, M ;
Cascarano, GL ;
Giacovazzo, C ;
Guagliardi, A ;
Moliterni, AGG ;
Polidori, G ;
Spagna, R .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119
[2]  
BEURSKENS PT, 1994, DIRDIF94 PROGRAM SYS
[3]  
Johnson C.K., 1976, Oak Ridge National Laboratory Report ORNL, P5138
[4]  
*MOL STRUCT CORP, 1992, MSC AFC DIFFR CONTR
[5]  
*MOL STRUCT CORP R, 2000, TEXSAN VERS 1 11
[6]   A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].
NORTH, ACT ;
PHILLIPS, DC ;
MATHEWS, FS .
ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&
[7]   trans-diaquabis(quinoline-2-carboxylato-N,O)-nickel(II)-water-ethanol (1/2/2) [J].
Odoko, M ;
Muranishi, Y ;
Okabe, N .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 :m267-m269
[8]   trans-diaquabis(2-quinolinecarboxylato-N,O)iron(II)-ethanol-water (1/2/2) [J].
Okabe, N ;
Makino, T .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 :1279-1280
[9]   Cobalt(II) and nickel(II) complexes of quinoline-2-carboxylate [J].
Okabe, N ;
Muranishi, Y .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 (06) :M228-M230
[10]   Aquabis(quinoline-2-carboxylato-κ2N,O)zinc(II) [J].
Okabe, N ;
Muranishi, Y .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 :M244-M246