Epitaxial CdSe-Au Nanocrystal Heterostructures by Thermal Annealing

被引:136
作者
Figuerola, Albert [1 ]
van Huis, Marijn [2 ,3 ]
Zanella, Marco [1 ]
Genovese, Alessandro [1 ]
Marras, Sergio [1 ]
Falqui, Andrea [1 ]
Zandbergen, Henny W. [2 ]
Cingolani, Roberto [1 ]
Manna, Liberato [1 ]
机构
[1] Ist Italino Tecnol, I-16163 Genoa, Italy
[2] Delft Univ Technol, Kavli Inst Nanosci, NL-2628 CJ Delft, Netherlands
[3] Univ Antwerp, EMAT, B-2020 Antwerp, Belgium
关键词
Nanorods; nanocrystals; self-assembly; epitaxy; orientation relationship; interface; hybrid nanocrystals; gold; cadmium selenide; annealing; HYBRID NANOCRYSTALS; GOLD NANOPARTICLES; SEMICONDUCTOR NANORODS; SELECTIVE GROWTH; NANODUMBBELLS; NUCLEATION; DEPOSITION; INTERFACES; ELECTRON; OXIDE;
D O I
10.1021/nl101482q
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The thermal evolution of a collection of heterogeneous CdSe-Au nanosystems (Au-decorated CdSe nanorods, networks, vertical assemblies) prepared by wet-chemical approaches was monitored in situ in the transmission electron microscope. In contrast to interfaces that are Formed during kinetically controlled wet chemical synthesis, heating under vacuum conditions results in distinct and well-defined CdSe/Au interfaces, located at the CdSe polar surfaces. The high quality of these interfaces should make the heterostructures more suitable for use in nanoscale electronic devices.
引用
收藏
页码:3028 / 3036
页数:9
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