Coating synthesis and enhanced photoluminescence of NaCl@LiLa (MoO4)2:Eu3+

被引:8
作者
Wang, Tianman [1 ]
Nong, Rong [1 ,3 ]
Gao, Yong [1 ]
Zhang, Xuzi [1 ]
Tan, Zanru [1 ]
Jian, Lipeng [1 ]
Liao, Sen [1 ]
Huang, Yingheng [1 ,2 ]
Zhang, Huaxin [1 ]
机构
[1] Guangxi Univ, Sch Chem & Chem Engn, Guangxi Coll & Univ Key Lab Appl Chem Technol & R, Nanning 530004, Guangxi, Peoples R China
[2] Guangxi Univ, Sch Mat Sci & Engn, Nanning 530004, Guangxi, Peoples R China
[3] Guangxi Polytech Vocat & Tech Coll, Chongzuo 532200, Guangxi, Peoples R China
基金
中国国家自然科学基金;
关键词
Inorganic compounds; Optical materials; Chemical synthesis; Luminescence; Optical properties; RARE-EARTH IONS; LUMINESCENCE PROPERTIES; NA+; NANOPHOSPHORS; INTENSITIES; PHOSPHORS; EMISSION; LI+;
D O I
10.1016/j.matlet.2017.04.098
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A series of NaCl@LiLa(MoO4)(2):0.05Eu(3+) (denoted as NaCl@LLMO:0.05Eu(3+)) were prepared by a simple coating method. Dual emission properties induced by coating NaCl are discussed. The influence of coating NaCl on the luminescence properties of Eu3+ ions were studied. The coating of NaCl results in much more influence on the emission intensities than on the R values (R = I-2/I-1, where I-2 and I-1 are the peak area of D-5(0) -> F-7(2) and D-5(0) -> F-7(1) emissions of Eu3+ ions, respectively) of Eu3+ ions in these samples. The optimal coating content of NaCl is 48 wt% with the corresponding sample (NaCl)(0.48 wt)@ LLMO:0.05Eu(3+), whose PL intensity is as high as 1.79 times of that without coating NaCl. (NaCl)(0.48wt)@LLMO:0.05Eu(3+) is a potential red-emitting phosphor with high R values (R = 8.29) for blue light-based white LED. (C) 2017 Published by Elsevier B.V.
引用
收藏
页码:77 / 81
页数:5
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