Influence of Real-World Engine Load Conditions on Nanoparticle Emissions from a DPF and SCR Equipped Heavy-Duty Diesel Engine

被引:43
作者
Thiruvengadam, Arvind [1 ]
Besch, Marc C. [1 ]
Carder, Daniel K. [1 ]
Oshinuga, Adewale [2 ]
Gautam, Mridul [1 ]
机构
[1] W Virginia Univ, Mech & Aerosp Dept, Morgantown, WV 26505 USA
[2] S Coast Air Qual Management Dist, Diamond Bar, CA 91765 USA
关键词
Catalysts - Selective catalytic reduction - Nanoparticles - Diesel engines - Nucleation;
D O I
10.1021/es203079n
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The experiments aimed at investigating the effect of real-world engine load conditions on nanopartide emissions from a Diesel Particulate Filter and Selective Catalytic Reduction after-treatment system (DPF-SCR) equipped heavy-duty diesel engine. The results showed the emission of nucleation mode particles in the size range of 6-15 nm at conditions with high exhaust temperatures. A direct result of higher exhaust temperatures (over 380 degrees C) contributing to higher concentration of nucleation mode nanoparticles is presented in this study. The action of an SCR catalyst with urea injection was found to increase the particle number count by over an order of magnitude in comparison to DPF out particle concentrations. Engine operations resulting in exhaust temperatures below 380 degrees C did not contribute to significant nucleation mode nanoparticle concentrations. The study further suggests the fact that SCR-equipped engines operating within the Not-To-Exceed (NTE) zone over a critical exhaust temperature and under favorable ambient dilution conditions could contribute to high nanoparticle concentrations to the environment. Also, some of the high temperature modes resulted in DPF out accumulation mode (between 50 and 200 nm) particle concentrations an order of magnitude greater than typical background PM concentrations. This leads to the conclusion that sustained NTE operation could trigger high temperature passive regeneration which in turn would result in lower filtration efficiencies of the DPF that further contributes to the increased solid fraction of the PM number count.
引用
收藏
页码:1907 / 1913
页数:7
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