A new polymorph of 2,5-bis(4-pyridyl)-1,3,4-thiadiazole

被引:4
作者
Zhao, XJ [1 ]
Cai, H [1 ]
Du, M [1 ]
机构
[1] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300074, Peoples R China
关键词
D O I
10.1107/S1600536805022142
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A new polymorph of 2,5-bis(4-pyridyl)-1,3,4-thiadiazole, C12H8N4S, obtained under hydrothermal conditions, is described. In this structure, the two terminal pyridyl groups are inclined to the central thiadiazole ring with dihedral angles of 6.47 (2) and 29.95 (5)degrees, and the dihedral angle between the pyridyl ring planes is 23.65 (6)degrees. An intermolecular C-H center dot center dot center dot N weak interaction is observed. The structural differences of two polymorphs of 2,5-bis(4-pyridyl)-1,3,4-thiadiazole are also discussed.
引用
收藏
页码:O2547 / O2548
页数:2
相关论文
共 6 条
[1]  
*BRUK AXS INC, 2003, APEX2
[2]  
*BRUK AXS INC, 2001, SAINT SHELXTL
[3]   2,5-Bis(4-pyridyl)-1,3,4-thiadiazole [J].
Du, M ;
Zhao, XJ ;
Li, CP .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 :O706-O707
[4]  
Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR
[5]  
Sheldrick G.M., 1996, SADABS VERSION 2008
[6]   Single-crystal structure validation with the program PLATON [J].
Spek, AL .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :7-13