Synthesis, Structure and Luminescent Property of Cadmium(II) Complex of Sulphosalicylic Acid

被引：0

作者：

Wu Gang ^{[1
]}

Wang Xiao-Feng ^{[2
]}

Wei Hao ^{[1
]}

Yu Li ^{[1
]}

机构：

[1] Chuzhou Univ, Dept Chem & Life Sci, Chuzhou 239012, Anhui, Peoples R China

[2] Xiaozhuang Univ, Coll Biochem & Environm Engn, Nanjing 211171, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 27卷 / 02期

关键词：

Cd(II) complex; 2,2-bipyridine; sulphosalicylic acid; luminescent property; METAL-ORGANIC FRAMEWORK; CRYSTAL-STRUCTURE; CHAIN; FLUORESCENCE;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new complex, [Cd(hssal)(bipy)(H2O)(2)]center dot H2O (1) (H(2)hssal: sulphosalicylic acid, bipy: 2,2'-bipyridine), is a metal-carboxylate coordination polymer prepared by hydrothermal synthesis techniques and characterized by single crystal X-ray diffraction and elemental analysis. Complex 1 crystallizes in monoclinic space group P2(1)/c and has 1D chain-like architecture. The crystal structure reveals that Cd(II) centre adopts a pseudo octahedral geometry. Ligand 2,2'-bipyridine chelates with Cd(II) atom. Hssal(2-) acts as a bridge coordinating to two different Cd(II) centers to give rise to a 1D infinite stepped chain polymer. 1D chains of 1 are connected together to form 3D structure through O-H center dot center dot center dot O hydrogen bond. The luminescent property of complex 1 was also studied. CCDC: 772715.

引用

页码：382 / 386

页数：5

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