Remote functionalization reactions in steroids

被引：47
作者：
Reese, PB [1 ]
机构：
[1] Univ W Indies, Dept Chem, Kingston 7, Jamaica
来源：
STEROIDS | 2001年 / 66卷 / 06期
关键词：
remote functionalization; steroid;
D O I：
10.1016/S0039-128X(00)00219-1
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Work published over the last thirty pears on the functionalization of unactivated positions in the steroid skeleton has been reviewed. (C) 2001 Elsevier Science Inc. All rights reserved.
引用
收藏
页码：481 / 497
页数：17
相关论文
共 86 条
[1]   3 BETA-AZIDOFORMATE THERMOLYSIS AS A METHOD FOR FUNCTIONALIZING 4 ALPHA-METHYL GROUP OF LANOSTAN-3-BETA-OL AND SIMILAR SYSTEMS [J].
ALEWOOD, PF ;
BENN, M ;
WONG, J ;
JONES, AJ .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1977, 55 (13) :2510-2516
[2]   NITRITE PHOTOLYSIS IN PRESENCE OF OXYGEN - IMPROVED SYNTHESIS OF 32-OXYGENATED LANOSTANES [J].
ALLEN, J ;
BOAR, RB ;
MCGHIE, JF ;
BARTON, DHR .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1973, (20) :2402-2404
[3]   DIRECT OXYFUNCTIONALIZATION AT UNACTIVATED SITES - SYNTHESIS OF 5-BETA-HYDROXYSTEROIDS BY PERFLUORODIALKYLOXAZIRIDINES [J].
ARNONE, A ;
CAVICCHIOLI, M ;
MONTANARI, V ;
RESNATI, G .
JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (19) :5511-5513
[4]   OXIDATIVE CYCLIZATION AND FRAGMENTATION OF STEROIDAL ALCOHOLS INDUCED BY CERIC AMMONIUM-NITRATE [J].
BALASUBRAMANIAN, V ;
ROBINSON, CH .
TETRAHEDRON LETTERS, 1981, 22 (06) :501-504
[5]   SIET-SPECIFIC DEHYDROGENATION OF RING-D IN STEROIDS [J].
BALDWIN, JE ;
BHATNAGA.AK ;
HARPER, RW .
JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1970, (11) :659-&
[6]   DOUBLE FUNCTIONALIZATION OF CHOLESTANOL DIRECTED BY SELECTIVE BIFUNCTIONAL TEMPLATES [J].
BATRA, R ;
BRESLOW, R .
TETRAHEDRON LETTERS, 1989, 30 (05) :535-538
[7]   SYNTHESIS OF SOME 32-FUNCTIONALIZED LANOSTANE DERIVATIVES [J].
BATTEN, PL ;
BARTON, DHR ;
BENTLEY, TJ ;
BOAR, RB ;
MCGHIE, JF ;
DRAPER, RW .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1972, (05) :739-&
[8]   REMOTE HYDROXYLATION OF A STEROID D-RING BY A FREE-RADICAL PROCESS [J].
BEGUE, JP ;
LEFORT, D ;
THAC, TD .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (20) :1086-1087
[9]   OXYFUNCTIONALIZATION OF STEROIDS BY DIOXIRANES - SITE AND STEREOSELECTIVE C-14 AND C-17 HYDROXYLATION OF PREGNANE AND ANDROSTANE STEROIDS [J].
BOVICELLI, P ;
LUPATTELLI, P ;
FIORINI, V ;
MINCIONE, E .
TETRAHEDRON LETTERS, 1993, 34 (38) :6103-6104
[10]   A HIGHLY REGIOSELECTIVE AND STEREOSELECTIVE-C5 OXYFUNCTIONALIZATION OF COPROSTANE STEROIDS BY DIOXIRANES - AN IMPROVED ACCESS TO PROGESTOGEN AND ANDROGEN HORMONES [J].
BOVICELLI, P ;
GAMBACORTA, A ;
LUPATTELLI, P ;
MINCIONE, E .
TETRAHEDRON LETTERS, 1992, 33 (48) :7411-7412
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