Investigation of structural, morphological and optical properties of nickel zinc oxide films prepared by sol-gel method

被引:23
作者
Dogan, D. Duygu [1 ]
Caglar, Yasemin [1 ]
Ilican, Saliha [1 ]
Caglar, Mujdat [1 ]
机构
[1] Anadolu Univ, Dept Phys, TR-26470 Eskisehir, Turkey
关键词
NiZnO; Sol-gel process; Crystalline structure; Absorption edge; NI-DOPED ZNO; THIN-FILMS;
D O I
10.1016/j.jallcom.2010.11.054
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
NiZnO films have been prepared on glass substrates by sol-gel spin coating method. Nickel (II) nitrate hexahyrate and zinc acetate dihydrate were used as precursors. Surface morphology and crystalline structure of the films were investigated by field emission scanning electron microscopy (FESEM) and X-ray diffractometer, respectively. X-ray diffraction (XRD) patterns showed that the films are polycrystalline nature. It was observed that crystal structure changed from wurtzite (ZnO) to cubic (NiO) structure. The lattice constants crystallite size and preferred orientation were calculated from XRD data. The surface morphology of the films changed with Ni concentration. The average transmittance of the ZnO film decreased from 84% to 58% in the visible region. The absorption edge varied from 3.26 to 3.89 eV with increasing Ni concentration. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:2461 / 2465
页数:5
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