Silver(I) complex of a new imino-N-heterocyclic carbene and ligand transfer to palladium(II) and rhodium(I)

被引：73

作者：

Coleman, KS ^{[1
]}

Chamberlayne, HT ^{[1
]}

Turberville, S ^{[1
]}

Green, MLH ^{[1
]}

Cowley, AR ^{[1
]}

机构：

[1] Univ Oxford, Inorgan Chem Lab, S Parks Rd, Oxford OX1 3QR, England

来源：

DALTON TRANSACTIONS | 2003年 / 14期

关键词：

D O I：

10.1039/b304474b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new imino-N-heterocyclic carbene ligand precursor [1-(2,4,6-Me3C6H2) imidazolium-3-{CH2C(t-Bu)=N(i-Pr)}] bromide has been synthesised and structurally characterised. The silver(I) complex [Ag(C(boolean AND)imine)(2)] AgBr2, where (C(boolean AND)imine) = 1-(2,4,6- Me3C6H2) imidazol-2-ylidene-3-{CH2C(t-Bu)=N(i- Pr)}, was readily prepared by reaction with Ag2O. Transfer of the ligand from silver(I) to palladium(II) and rhodium(I) by reaction with [PdCl2(MeCN)(2)] and [Rh(cod)(THF)(2)][BF4] led to the tautomerisation of the imine moiety to the enamine affording the structurally characterised complex [PdCl2(C(boolean AND)enamine)] and [ Rh( cod)(C(boolean AND)enamine)][BF4] respectively, where (C(boolean AND)enamine) = 1-(2,4,6-Me3C6H2) imidazol-2-ylidene-3-{CH=C(t-Bu) NH(i-Pr)}.

引用

页码：2917 / 2922

页数：6

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