Syntheses, Crystal Structures and Properties of Two New Zn Based Boron Imidazolate Frameworks

被引：0

作者：

Bi Ming-Yue ^{[1
,2
]}

Wen Yi-Hang ^{[1
]}

Zhang Hai-Xia ^{[2
]}

Zhang Jian ^{[2
]}

机构：

[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Zhejiang, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2021年 / 40卷 / 07期

关键词：

boron imidazolate frameworks; crystal structure; X-ray crystallography; luminescent; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; INHIBITORS; DESIGN; CO2;

D O I：

10.14102/j.cnki.0254-5861.2011-3068

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new boron imidazolate frameworks (BIFs), Zn-2[HBH(2-mim)(3)](2)(1,2-PEA)(2)(EG)(2) (BIF-120, EG = ethylene glycol) and Zn[BH(2-mim)(3)](1,2-HPEA) (BIF-121), were successfully synthesized by mixing the KBH(2-mim)(3)] ligand and the semirigid aromatic dicarboxylate ligand 1,2-benzenediacetic acid (1,2-H(2)PEA) under solvothermal conditions. In this paper, the two samples were structurally characterized by single-crystal X-ray diffraction and tested by infrared spectroscopy (IR), UV-visible spectroscopy (UV-Vis), thermogravimetric analysis TGA and X-ray powder diffractions. In addition, the solid-state luminescent properties of these crystals were also investigated.

引用

页码：865 / 870

页数：6

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