Steam pyrolysis of N, N, N', N' - Tetrabutyl diglycolamide (TBDGA) part-I: Experimental investigations

被引:0
作者
Dicholkar, Deepak D. [1 ]
Gaikar, Vilas G. [1 ]
Kumar, Shekhar [2 ]
Natarajan, R. [2 ]
机构
[1] Inst Chem Technol, Chem Engn Dept, Mumbai 400019, Maharashtra, India
[2] Indira Gandhi Ctr Atom Res, Proc Dev & Equipment Sect, Reproc Grp, Kalpakkam 603102, Tamil Nadu, India
关键词
High level nuclear waste; Tetrabutyldiglycolamide; TODGA; Nuclear waste management; Steam pyrolysis; HIGH-LEVEL WASTE; SUPPORTED LIQUID-MEMBRANE; COUNTER-CURRENT EXTRACTION; NUCLEAR-WASTE; NITRIC-ACID; N; N'; N'-TETRAOCTYL DIGLYCOLAMIDE; PROMISING EXTRACTANTS; TODGA; ACTINIDE; HYDROCARBONS;
D O I
10.1016/j.jaap.2017.06.017
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Steam pyrolysis of N,N,N',N'-tetrabutyldiglycolamide (TBDGA) is investigated in a non-catalytic tubular reactor for complete gasification as a waste management method for solvents used in Nuclear Industry. A total of 19 products have been identified in the product streams and quantified to get complete material balance under varying operating conditions of the process at atmospheric pressure. The optimized reaction parameters for the complete gasification of TBDGA were temperature of 1050 degrees C, water to TBDGA molar ratio of 124 and TBDGA's flow rate of 5.7 g h(-1).
引用
收藏
页码:132 / 142
页数:11
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