Single-step fabrication of Li1-xNi1+xOx and LiCoO2 films by soft solution-processing at 20-200°C

被引：17

作者：

Han, KS ^{[1
]}

Song, SW ^{[1
]}

Fujita, H ^{[1
]}

Yoshimura, M ^{[1
]}

机构：

[1] Tokyo Inst Technol, Ctr Mat Design Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 226, Japan

来源：

SOLID STATE IONICS | 2000年 / 135卷 / 1-4期

基金：

日本学术振兴会;

关键词：

lithium microbattery; hydrothermal; electrochemical; solution processing; Li1-xNi1+xO2 films; LiCoO2; films;

D O I：

10.1016/S0167-2738(00)00444-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Li1-xNi1+xO2 and LiCoO2 films as cathodes for lithium rechargeable microbatteries were fabricated in a concentrated LiOH solution at 20-200 degreesC using different Soft Solution-Processing methods. While LiCoO2 films can be obtained by a purely hydrothermal reaction, a supplementary electrochemical charge with the same hydrothermal conditions is necessary to produce Li1-xNi1+xO2 films. A film formation mechanism study elucidated the necessity of such different activation methods for the preparation of Li1-xNi1+xO2 and LiCoO2 films. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：273 / 276

页数：4

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