Molybdenum-vanadium-based molecular sieves with microchannels of seven-membered rings of corner-sharing metal oxide octahedra

被引：88

作者：

Sadakane, Masahiro ^{[1
]}

Kodato, Katsunori ^{[1
]}

Kuranishi, Takao ^{[1
]}

Nodasaka, Yoshinobu ^{[2
]}

Sugawara, Kenji ^{[3
]}

Sakaguchi, Norihito ^{[3
]}

Nagai, Takuro ^{[4
]}

Matsui, Yoshio ^{[4
]}

Ueda, Wataru ^{[1
]}

机构：

[1] Hokkaido Univ, Ctr Catalysis Res, Sapporo, Hokkaido 0010021, Japan

[2] Hokkaido Univ, Grad Sch Dent Med, Electron Microscopy Lab, Sapporo, Hokkaido 0608586, Japan

[3] Hokkaido Univ, High Voltage Electron Microscope Lab, Sapporo, Hokkaido 0608626, Japan

[4] Natl Inst Mat Sci, Adv Electrom Microscopy Grp, Adv Nanocharacterizat Ctr, Tsukuba, Ibaraki 3050044, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 13期

关键词：

hydrothermal synthesis; microporous materials; molybdenum; vanadium;

D O I：

10.1002/anie.200705448

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Octahedral molecular sieves: Crystalline orthorhombic Mo3VOx (see SEM image), which was prepared by hydrothermal synthesis, contains microchannels made up of seven-membered rings of corner-sharing {MO6} octahedra. Small molecules such as methane, ethane, N2, Ar, CO2 can enter the microchannels of this compound, which exhibits the type I adsorption behavior typical of microporous materials. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2493 / 2496

页数：4

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