Synthetic Organic Electrochemistry in Ionic Liquids: The Viscosity Question

被引：14

作者：

Bornemann, Steven ^{[2
]}

Handy, Scott T. ^{[1
]}

机构：

[1] Middle Tennessee State Univ, Dept Chem, Murfreesboro, TN 37132 USA

[2] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA

来源：

MOLECULES | 2011年 / 16卷 / 07期

关键词：

room temperature ionic liquid; carbamate oxidation; constant current; viscosity; organic electrosynthesis; ELECTROORGANIC CHEMISTRY; AROMATIC-COMPOUNDS; HYDROGEN-PEROXIDE; SOLVENTS; ELECTROSYNTHESIS; REACTIVITY; EPOXIDATION; ACTIVATION; OXIDATION; FLUORINATION;

D O I：

10.3390/molecules16075963

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Ionic liquids are obvious candidates for use in electrochemical applications due to their ionic character. Nevertheless, relatively little has been done to explore their application in electrosynthesis. We have studied the Shono oxidation of arylamines and carbamates using ionic liquids as recyclable solvents and have noted that the viscosity of the medium is a major problem, although with the addition of sufficient co-solvent, good results and excellent recovery and recycling of the ionic liquid can be achieved.

引用

页码：5963 / 5974

页数：12

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