Fabrication of titanium doped BiVO4 as a novel visible light driven photocatalyst for degradation of residual tetracycline pollutant

被引:32
作者
Nguyen Thi Khanh Huyen [1 ,7 ]
Thanh-Dong Pham [1 ,2 ]
Nguyen Thi Dieu Cam [3 ]
Pham Van Quan [4 ]
Nguyen Van Noi [1 ,2 ]
Nguyen Thi Hanh [5 ]
Mai Hung Thanh Tung [6 ]
Van-Duong Dao [7 ]
机构
[1] Vietnam Natl Univ, Univ Sci, Fac Chem, 334 Nguyen Trai, Hanoi, Vietnam
[2] Vietnam Natl Univ, Univ Sci, VNU Key Lab Adv Mat Green Growth, 334 Nguyen Trai, Hanoi, Vietnam
[3] Quy Nhon Univ, Fac Nat Sci, 170 An Duong Vuong St, Quy Nhon, Binh Dinh, Vietnam
[4] Hue Ind Coll, 70 Nguyen Hue, Hue, Vietnam
[5] Vietnam Natl Univ, Univ Sci, Fac Environm Sci, 334 Nguyen Trai, Hanoi, Vietnam
[6] Ho Chi Minh City Univ Food Ind, Fac Chem Engn, 140 Le Trong Tan, Ho Chi Minh City, Vietnam
[7] Phenikaa Univ, Fac Biotechnol Chem & Environm Engn, Hanoi 10000, Vietnam
关键词
BiVO4; Titanium dopant; Photocatalysis; Tetracycline; Degradation; HYDROTHERMAL SYNTHESIS; AG NANOPARTICLES; WATER; PERFORMANCE; HETEROJUNCTION; TRANSFORMATION; ANTIBIOTICS; EFFICIENCY; OXIDATION; FACET;
D O I
10.1016/j.ceramint.2021.08.335
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this study, titanium (Ti) was used as an active dopant to incorporate into BiVO4 lattice using the hydrothermal method. The synthesized BiVO4 and Ti-BiVO4 with 1, 5 and 10 wt% of Ti dopants have been applied for photocatalytic decomposition of Tetracycline under visible light irradiation. The characterized results showed that this synthesized BiVO4 and Ti-BiVO4 materials existed in a form of spherical particles. The particle sizes of the Ti-BiVO4 were much bigger than that of the BiVO4. However, Ti dopants effectively enhanced visible light absorption, decreased band gap energy as well as prevented electron-hole recombination of the BiVO4 leading to increase in photocatalytic activities of the doped materials. The obtained results from photocatalytic experiments indicated that the 5Ti-BiVO4, whose weight ratio of Ti was 5%, was the best material for TC degradation (78.49%). Recycling tests were consecutively carried out in 4 runs to demonstrate the stability of the BiVO4 photocatalyst with 5 wt% of Ti dopant.
引用
收藏
页码:34253 / 34259
页数:7
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