ω-Pentafluoro-λ6-sulfanyl(SF5)-n-perfluoroalkyl benzene derivatives

被引：6

作者：

Hodges, AM ^{[1
]}

Winter, R ^{[1
]}

Mohtasham, J ^{[1
]}

Bailey, P ^{[1
]}

Gard, GL ^{[1
]}

机构：

[1] Portland State Univ, Dept Chem, Portland, OR 97207 USA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2001年 / 110卷 / 01期

基金：

美国国家科学基金会;

关键词：

SF5(CF2)(n)-aromatics; perfluoroalkylaromatics; NMR and IR spectroscopy; mass spectrometry;

D O I：

10.1016/S0022-1139(01)00365-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of pentafluoro-lambda (6)-sulfanyl(SF5)-perfluoroalkyl iodides with benzene is a convenient route for preparing SF5-perfluoroalkyl benzene derivatives, SF5(CF2)(n)C6H5 (n = 2, 4, 6, 8), a new class of perfluoroalkylaromatic compounds. The preparation and characterization of these new materials are described. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：1 / 4

页数：4

共 21 条

[1]

BANKS EE, 1974, J CHEM SOC P1, P1266

[2] A new method for the synthesis of aromatic sulfurpentafluorides and studies of the stability of the sulfurpentafluoride group in common synthetic transformations [J].

Bowden, RD ;

Comina, PJ ;

Greenhall, MP ;

Kariuki, BM ;

Loveday, A ;

Philp, D .

TETRAHEDRON, 2000, 56 (21) :3399-3408

[3]

BROWN JK, 1965, ADV FLUORINE CHEM, V4, P258

[4] THE INFRA-RED SPECTRA OF SOME DERIVATIVES OF SULPHUR HEXAFLUORIDE [J].

CROSS, LH ;

CUSHING, G ;

ROBERTS, HL .

SPECTROCHIMICA ACTA, 1961, 17 (03) :344-351

[5]

GARD GL, 1969, Patent No. 1167228

[6]

GARD GL, 1970, Patent No. 3506774

[7] SYNTHESIS + CHEMISTRY OF ETHYNYLSULFUR PENTAFLUORIDE [J].

HOOVER, FW ;

COFFMAN, DD .

JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (12) :3567-&

[8] A ROUTE TO FLUOROALKYL-SUBSTITUTED AROMATIC COMPOUNDS INVOLVING FLUOROALKYLCOPPER INTERMEDIATES [J].

MCLOUGHL.VC ;

THROWER, J .

TETRAHEDRON, 1969, 25 (24) :5921-&

[9] A facile preparation of ICF2CF2I and its reaction with ethylene [J].

Renn, JA ;

Toney, AD ;

Terjeson, RJ ;

Gard, GL .

JOURNAL OF FLUORINE CHEMISTRY, 1997, 86 (01) :113-114

[10] PREPARATION AND SOME REACTIONS OF DISULPHUR DECAFLUORIDE [J].

ROBERTS, HL .

JOURNAL OF THE CHEMICAL SOCIETY, 1962, (AUG) :3183-&

← 1 2 3 →