Preparation and luminescence property of Dy3+-doped YPO4 phosphors

被引:72
作者
Lai, Hua [1 ]
Bao, Amurisana [1 ]
Yang, Yuming [1 ]
Xu, Weiwei [1 ]
Tao, Yanchun [2 ]
Yang, Hua [1 ]
机构
[1] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China
[2] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China
基金
中国国家自然科学基金;
关键词
co-precipitation; photoluminescence; nanocrystals; phosphate; lithium;
D O I
10.1016/j.jlumin.2007.09.027
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The co-precipitation reaction soft chemistry method was employed to prepare fine Y-PO4:Dy3+ phosphor particles calcined at 950 degrees C. Adjusting appropriate pH and introducing lithium may greatly affect the particle size of the product and further affect the luminescence intensity. The as-prepared samples were characterized by X-ray diffraction (XRD), transmission electron micrograph (TEM) and photoluminescence (PL) spectroscopy. The obtained YPO4 nanocrystals appeared to be spherical with some agglomeration and their sizes ranged from 20 to 40nm. The characteristic transitions of Dy3+ due to F-4(9/2) -> H-6(15/2) (blue) and F-4(9/2) -> H-6(13/2) (yellow) were detected in the emission spectra. (c) 2007 Published by Elsevier B.V.
引用
收藏
页码:521 / 524
页数:4
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