Vapor-Liquid Equilibrium and Liquid-Liquid Equilibrium of Methyl Acetate plus Methanol+1-Ethyl-3-methylimidazolium Acetate

被引：74
|
作者：
Cai, Jialin [1 ]
Cui, Xianbao [1 ]
Zhang, Ying [1 ]
Li, Rui [1 ]
Feng, Tianyang [1 ]
机构：
[1] Tianjin Univ, State Key Lab Chem Engn, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2011年 / 56卷 / 02期
关键词：
TERT-BUTYL ETHER; IONIC LIQUIDS; METHANOL; 1-ETHYL-3-METHYLIMIDAZOLIUM; MIXTURES; ETHANOL; TETRAFLUOROBORATE; SEPARATION; SOLVATION; WATER;
D O I：
10.1021/je100932m
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Vapor-liquid equilibrium (VLE) and liquid-liquid equilibrium (LLE) were measured for the ternary system of methyl acetate + methanol + 1-ethyl-3-methylimidazolium acetate ([EMIM][Ac]). The experimental LLE data were correlated by the NRTL model and the binary interaction parameters obtained from LLE were used to predict the ternary V:LE, and the results agreed well with the experimental data. The results showed that the ionic liquid ([EMIM][Ac]) produced a notable salting-out effect, which enhanced the relative volatility of methyl acetate and methanol.
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收藏
页码：282 / 287
页数：6
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