A Nanospherical Mesoporous Ruthenium-Containing Polymer as a Guaiacol Hydrogenation Catalyst

被引：7
作者：
Boronoev, M. P. [1 ]
Shakirov, I. I. [1 ]
Ignat'eva, V. I. [1 ]
Maximov, A. L. [1 ,2 ]
Karakhanov, E. A. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119991, Russia
[2] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119991, Russia
来源：
PETROLEUM CHEMISTRY | 2019年 / 59卷 / 12期
基金：
俄罗斯科学基金会;
关键词：
mesoporous polymer; nanospheres; nanoparticles; ruthenium; guaiacol; hybrid catalyst; hydrogenation; CARBON; HYDRODEOXYGENATION; NANOPARTICLES; PLATINUM; OXYGEN;
D O I：
10.1134/S096554411912003X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A hybrid catalyst is synthesized using ruthenium nanoparticles deposited on a nanospherical mesoporous polymer. Catalytic properties are studied in guaiacol hydrogenation at a temperature of 200-250 degrees C and a hydrogen pressure of 5.0 MPa. Effect of solvent and catalytic additives on the reaction is investigated. It is shown that the synthesized catalyst exhibits the highest activity in guaiacol hydrodeoxygenation in the two-phase system water/n-dodecane and when the reaction is carried out in the presence of scandium triflate.
引用
收藏
页码：1300 / 1306
页数：7
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