Thermal characterization of Ge-As-Se glasses by differential scanning calorimetry

被引:32
作者
Wang, R. P. [1 ]
Zha, C. J. [1 ]
Rode, A. V. [1 ]
Madden, S. J. [1 ]
Luther-Davies, B. [1 ]
机构
[1] Australian Natl Univ, Res Sch Phys Sci & Engn, Laser Phys Ctr, Ctr Ultrahigh Bandwidth Device Opt Syst CUDOS, Canberra, ACT 0200, Australia
关键词
D O I
10.1007/s10854-007-9229-1
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Differential scanning calorimetry (DSC) was performed at different heating rates under non-isothermal conditions to probe the glass transition kinetics of several Ge-As-Se glasses with different chemical compositions. The change of the glass transition temperature T. with the heating rate and composition was investigated and the activation energy of the glass transition was estimated. The fragility index was calculated and the correlation to the mean coordination number of Ge-As-Se glasses was discussed.
引用
收藏
页码:S419 / S422
页数:4
相关论文
共 18 条
[1]   CORRELATIONS OF THE NONEXPONENTIALITY AND STATE DEPENDENCE OF MECHANICAL RELAXATIONS WITH BOND CONNECTIVITY IN GE-AS-SE SUPERCOOLED LIQUIDS [J].
BOHMER, R ;
ANGELL, CA .
PHYSICAL REVIEW B, 1992, 45 (17) :10091-10094
[2]   NONEXPONENTIAL RELAXATIONS IN STRONG AND FRAGILE GLASS FORMERS [J].
BOHMER, R ;
NGAI, KL ;
ANGELL, CA ;
PLAZEK, DJ .
JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (05) :4201-4209
[3]   Nanoscale phase separation effects near (r)over-bar=2.4 and 2.67, and rigidity transitions in chalcogenide glasses [J].
Boolchand, P ;
Georgiev, DG ;
Qu, T ;
Wang, F ;
Cai, LC ;
Chakravarty, S .
COMPTES RENDUS CHIMIE, 2002, 5 (11) :713-724
[4]   Neutron inelastic scattering study of Se-As-Ge glasses: A test of the vibrational isocoordinate rule [J].
Effey, B ;
Cappelletti, RL .
PHYSICAL REVIEW B, 1999, 59 (06) :4119-4124
[5]  
KASAP SO, 1990, PHYS CHEM GLASSES, V31, P71
[6]   On the glass transition temperature in covalent glasses [J].
Kerner, R ;
Micoulaut, M .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1997, 210 (2-3) :298-305
[7]   Evidence for nanoscale phase separation of stressed-rigid glasses [J].
Mamedov, S ;
Georgiev, DG ;
Qu, T ;
Boolchand, P .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (31) :S2397-S2411
[8]   Structural investigation of chalcogenide and chalcohalide glasses using Raman spectroscopy [J].
Nguyen, VQ ;
Sanghera, JS ;
Freitas, JA ;
Aggarwal, ID ;
Lloyd, IK .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1999, 248 (2-3) :103-114
[9]   TOPOLOGY OF COVALENT NON-CRYSTALLINE SOLIDS .1. SHORT-RANGE ORDER IN CHALCOGENIDE ALLOYS [J].
PHILLIPS, JC .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1979, 34 (02) :153-181
[10]  
Popescu MA., 2001, Non-crystalline chalcogenicides