Study of Static and Dynamic Behavior of a Membrane Reactor for Hydrogen Production

被引：4

作者：

Alqahtani, Rubayyi T. ^{[1
]}

Ajbar, Abdelhamid ^{[2
]}

Bhowmik, Samir Kumar ^{[3
]}

Alghamdi, Rabab Ali ^{[1
]}

机构：

[1] Imam Mohammad Ibn Saud Islamic Univ IMSIU, Coll Sci, Dept Math & Stat, Riyadh 11432, Saudi Arabia

[2] King Saud Univ, Dept Chem Engn, Riyadh 11421, Saudi Arabia

[3] Univ Dhaka, Dept Math, Dhaka 1000, Bangladesh

来源：

PROCESSES | 2021年 / 9卷 / 12期

关键词：

membrane reactor; hydrogen; ammonia; permeation; multiple steady states; AMMONIA DECOMPOSITION; STORAGE; PERMEATION;

D O I：

10.3390/pr9122275

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The paper investigates the stability and bifurcation phenomena that can occur in membrane reactors for the production of hydrogen by ammonia decomposition. A simplified mixed model of the membrane reactor is studied and two expressions of hydrogen permeation are investigated. The effect of the model design and operating parameters on the existence of steady state multiplicity is discussed. In this regard, it is shown that the adsorption-inhibition effect caused by the competitive adsorption of ammonia can lead to the occurrence of multiple steady states in the model. The steady state multiplicity exists for a wide range of feed ammonia concentration and reactor residence time. The effect of the adsorption constant, the membrane surface area and its permeability on the steady state multiplicity is delineated. The analysis also shows that no Hopf bifurcation can occur in the studied model.

引用

页数：15

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