Novel separation strategies based on molecularly imprinted adsorbents

被引:63
作者
Joshi, VP [1 ]
Karode, SK [1 ]
Kulkarni, MG [1 ]
Mashelkar, RA [1 ]
机构
[1] Natl Chem Lab, Div Chem Engn, Poona 411008, Maharashtra, India
关键词
molecular imprinting; selective sorbents; trace impurity removal;
D O I
10.1016/S0009-2509(98)00033-5
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The use of molecularly imprinted polymers (MIPs) for the separation of structurally similar substrates is demonstrated, with a model system comprising removal of phenol from anisole. It is shown experimentally that the shape and size of the cavity determines the selectivity of separation. Hydrogen bonding plays a key role in achieving the separation. For the MIPs synthesised in this work, equilibrium sorption, packed-bed flow experiments as well as batch experiments were conducted. The results were analysed in the framework of a suitable mathematical model. Agreement between the experimental and predicted breakthrough curves was sound. MIPs could be used to achieve such separations in commercially important systems, especially for the removal of trace impurities. The recovery as well as selectivity can be further improved by selecting sorbents resistant to swelling. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2271 / 2284
页数:14
相关论文
共 31 条
[1]  
ANDERSSON LI, 1990, J CHROMATOGR, V654, P31
[2]   CONCENTRATION OF MACROMOLECULES FROM AQUEOUS-SOLUTIONS - A NEW SWELLEX PROCESS [J].
BADIGER, MV ;
KULKARNI, MG ;
MASHELKAR, RA .
CHEMICAL ENGINEERING SCIENCE, 1992, 47 (01) :3-9
[3]   PARA-CARBOXYSTYRENE - WITTIG PROCEDURE IN AQUEOUS-MEDIUM [J].
BROOS, R ;
TAVERNIER, D ;
ANTEUNIS, M .
JOURNAL OF CHEMICAL EDUCATION, 1978, 55 (12) :813-813
[4]   ORGANIC MICROPOROUS MATERIALS MADE BY BICONTINUOUS MICROEMULSION POLYMERIZATION [J].
BURBAN, JH ;
HE, MT ;
CUSSLER, EL .
AICHE JOURNAL, 1995, 41 (04) :907-914
[5]   LONGITUDINAL DISPERSION OF LIQUID FLOWING THROUGH FIXED AND FLUIDIZED BEDS [J].
CHUNG, SF ;
WEN, CY .
AICHE JOURNAL, 1968, 14 (06) :857-&
[6]   SURFACE GRAFTING OF FUNCTIONAL POLYMERS TO MACROPOROUS POLY(TRIMETHYLOLPROPANE TRIMETHACRYLATE) [J].
DHAL, PK ;
VIDYASANKAR, S ;
ARNOLD, FH .
CHEMISTRY OF MATERIALS, 1995, 7 (01) :154-162
[7]   PREDICTION OF ULTIMATE SEPARATION IN PARAMETRIC PUMPS [J].
FOO, SC ;
RICE, RG .
AICHE JOURNAL, 1975, 21 (06) :1149-1158
[8]  
GUSSLER GM, 1993, IND ENG CHEM RES, V32, P2727
[9]  
HORSTMANN BJ, 1989, CHEM ENG RES DES, V67, P243
[10]   ADSORPTION OF O-CRESOL AND BENZOIC-ACID IN AN ADSORBER PACKED WITH AN ION-EXCHANGE RESIN - A COMPARATIVE-STUDY OF DIFFUSIONAL MODELS [J].
HUANG, RT ;
CHEN, TL ;
WENG, HS .
SEPARATION SCIENCE AND TECHNOLOGY, 1994, 29 (15) :2019-2033