A Transition-Metal-Free Homogeneous TEMPO-Based Catalyst: Aerobic Oxidation of Alcohols in Aqueous Media

被引：7

作者：

Laeini, Mohammad Sadegh ^{[1
]}

Shaabani, Ahmad ^{[1
]}

机构：

[1] Shahid Beheshti Univ, Dept Chem, GC, POB 19396-4716, Tehran, Iran

来源：

CHEMISTRYSELECT | 2017年 / 2卷 / 28期

关键词：

Aerobic oxidation; Alcohol; Homogeneous Catalyst; TEMPO; NITROGEN-DOPED GRAPHENE; HIGHLY EFFICIENT; OXOAMMONIUM SALTS; MILD CONDITIONS; ALKYL ARENES; SELECTIVE OXIDATION; ORGANIC-COMPOUNDS; KETONES; ALDEHYDES; PHTHALOCYANINE;

D O I：

10.1002/slct.201701428

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this paper the use of a novel TEMPO-based transition metal free homogeneous catalyst system, TEMPO/NaNO2/NH4Br/1,1,3,3-tetramethylguanidine sulfonic acid, for the aerobic oxidation of various alcohols to the corresponding aldehydes and ketones is described. The reactions are carried out in aqueous acetonitrile under atmospheric pressure and ambient temperature. The catalytic system exhibits excellent activity for the selective aerobic oxidation of alcohols.

引用

页码：9084 / 9087

页数：4

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