Flexible metal-organic frameworks for gas storage and separation

被引：134

作者：

Li, Yue ^{[1
]}

Wang, Yutong ^{[1
]}

Fan, Weidong ^{[1
]}

Sun, Daofeng ^{[1
]}

机构：

[1] China Univ Petr East China, Sch Mat Sci & Engn, Coll Sci, State Key Lab Heavy Oil Proc, Qingdao 266580, Peoples R China

来源：

DALTON TRANSACTIONS | 2022年 / 51卷 / 12期

基金：

中国国家自然科学基金;

关键词：

BREATHING BEHAVIOR; SINGLE-CRYSTAL; ADSORPTION; MOF; CO2; SORPTION; MIL-53; FLEXIBILITY; PRESSURE; TEMPERATURE;

D O I：

10.1039/d1dt03842g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Flexible metal-organic frameworks (MOFs) have gradually attracted much attention due to their reversible structural changes and flexible structural responses. The basic research of flexible MOFs is to study their dynamic responses under different external stimuli and translate the responses into applications. Most research studies on flexible MOFs focus on gas storage and separation, but lack a systematic summary. Here, we review the development of flexible MOFs, the structural transformation under the external effects of temperature, pressure, and guest molecules, and their applications in gas storage and separation. Microporous MOFs with flexible structures provide unique opportunities for fine-tuning their performance because the pore shape and size can be controlled by external stimuli. The characteristics of breathing phenomena and large specific surface area make flexible MOFs suitable candidates for gas storage and separation. Finally, the application prospects of flexible MOFs are reported.

引用

页码：4608 / 4618

页数：11

共 102 条

[11] Thermal and Guest-Assisted Structural Transition in the NH2-MIL-53(Al) Metal Organic Framework: A Molecular Dynamics Simulation Investigation [J].

Boule, Roald ;

Roland, Claire ;

Le Polles, Laurent ;

Audebrand, Nathalie ;

Ghoufi, Aziz .

NANOMATERIALS, 2018, 8 (07)

[12] Adsorption induced transitions in soft porous crystals: An osmotic potential approach to multistability and intermediate structures [J].

Bousquet, David ;

Coudert, Franois-Xavier ;

Fossati, Alexandre G. J. ;

Neimark, Alexander V. ;

Fuchs, Alain H. ;

Boutin, Anne .

JOURNAL OF CHEMICAL PHYSICS, 2013, 138 (17)

[13] Experimental Evidence for Vibrational Entropy as Driving Parameter of Flexibility in the Metal-Organic Framework ZIF-4(Zn) [J].

Butler, Keith T. ;

Vervoorts, Pia ;

Ehrenreich, Michael G. ;

Armstrong, Jeff ;

Skelton, Jonathan M. ;

Kieslich, Gregor .

CHEMISTRY OF MATERIALS, 2019, 31 (20) :8366-8372

[14] Metal-Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications [J].

Cai, Guorui ;

Yan, Peng ;

Zhang, Liangliang ;

Zhou, Hong-Cai ;

Jiang, Hai-Long .

CHEMICAL REVIEWS, 2021, 121 (20) :12278-12326

[15]

Carrington EJ, 2017, NAT CHEM, V9, P882, DOI [10.1038/nchem.2747, 10.1038/NCHEM.2747]

[16] Flexible Metal-Organic Frameworks: Recent Advances and Potential Applications [J].

Chang, Ze ;

Yang, Dong-Hui ;

Xu, Jian ;

Hu, Tong-Liang ;

Bu, Xian-He .

ADVANCED MATERIALS, 2015, 27 (36) :5432-5441

[17] IM-19: a new flexible microporous gallium based-MOF framework with pressure- and temperature-dependent openings [J].

Chaplais, Gerald ;

Simon-Masseron, Angelique ;

Porcher, Florence ;

Lecomte, Claude ;

Bazer-Bachi, Delphine ;

Bats, Nicolas ;

Patarina, Joel .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (26) :5241-5245

[18] Pressure-Induced Amorphization and Porosity Modification in a Metal-Organic Framework [J].

Chapman, Karena W. ;

Halder, Gregory J. ;

Chupas, Peter J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (48) :17546-17547

[19] Flexible MOFs under stress: pressure and temperature [J].

Clearfield, Abraham .

DALTON TRANSACTIONS, 2016, 45 (10) :4100-4112

[20] Metal-organic frameworks under pressure [J].

Collings, Ines E. ;

Goodwin, Andrew L. .

JOURNAL OF APPLIED PHYSICS, 2019, 126 (18)

← 1 2 3 4 5 6 7 8 9 10 →