Top Laminated Graphene Electrode in a Semitransparent Polymer Solar Cell by Simultaneous Thermal Annealing/Releasing Method

被引：178

作者：

Lee, Yu-Ying ^{[1
]}

Tu, Kun-Hua ^{[1
]}

Yu, Chen-Chieh ^{[1
]}

Li, Shao-Sian ^{[1
]}

Hwang, Jeong-Yuan ^{[2
]}

Lin, Chih-Cheng ^{[1
]}

Chen, Kuei-Hsien ^{[3
]}

Chen, Li-Chyong ^{[2
]}

Chen, Hsuen-Li ^{[1
]}

Chen, Chun-Wei ^{[1
]}

机构：

[1] Natl Taiwan Univ, Taipei 106, Taiwan

[2] Natl Taiwan Univ, Ctr Condensed Matter Sci, Taipei 116, Taiwan

[3] Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan

来源：

ACS NANO | 2011年 / 5卷 / 08期

关键词：

graphene electrode; top lamination; semitransparent solar cell; polymer solar cell; roll-to-roll; TRANSPARENT; OXIDE; LAYER; PERFORMANCE; FILMS;

D O I：

10.1021/nn201940j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this article, we demonstrate a semitransparent inverted-type polymer solar cell using a top laminated graphene electrode without damaging the Underlying organic photoactive layer. The lamination process involves the simultaneous thermal releasing deposition of the graphene top electrode during thermal annealing of the photoactive layer. The resulting semitransparent polymer solar cell exhibits a promising power conversion efficiency of approximately 76% of that of the standard opaque device using an Ag metal electrode. The asymmetric. photovoltaic performances of the semitransparent solar cell While illuminated from two respective sides were further analyzed using optical simulation and photocarrier recombination measurement. The devices consisting of the top laminated transparent graphene electrode enable the feasible roll-to-roll manufacturing of low-cost semitransparent polymer solar cells and can be utilized in new applications such as power-generated windows or multijunction or bifacial photovoltaic devices.

引用

页码：6564 / 6570

页数：7

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