Research on the Diffusion Behavior of Cu in Low-Carbon Steel under High Temperatures

被引:6
作者
Li, Huirong [1 ]
Ma, Tao [1 ]
He, Yueying [1 ]
Li, Yungang [1 ]
机构
[1] North China Univ Sci & Technol, Coll Met & Energy, Tangshan 063009, Peoples R China
基金
中国国家自然科学基金;
关键词
Cu; low-carbon steel; diffusion coefficient; molecular dynamics; high-temperature annealing; CORROSION BEHAVIOR; COPPER;
D O I
10.3390/cryst12020207
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The effective diffusion of Cu in Fe is the key to forming a stable transition layer between copper and low-carbon steel, but it is seriously affected by several factors, especially temperature, and the diffusion of Cu can only be completed at high temperatures. In order to analyze the diffusion coefficient of Cu in low-carbon steel under high temperatures, and to obtain the best diffusion temperature range of Cu in steel, the electrodeposition method was used to prepare the diffusion couple of copper and low-carbon steel, which would be annealed under different temperatures for 6 h; meanwhile, the MD models were also used to analyze the diffusion behavior of Cu in Fe at different temperatures. The results show that the diffusion of Cu in low-carbon steel could be realized by high-temperature annealing, and as the temperature increases, the thickness of the Cu/low-carbon steel transition layer shows an increasing trend. When the annealing temperature is between 900 degrees C and 1000 degrees C, the thickness of the transition layer increases the fastest. The results of the MD models show that, when the temperature is in the phase transition zone, the main restrictive link for the diffusion of Cu in Fe is the phase transition process of Fe; additionally, when the temperature is higher, the main restrictive link for the diffusion of Cu in Fe is the activity of the atom.
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页数:17
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