Light-Controlled Conductance Switching in Azobenzene-Containing MWCNT-Polymer Nanocomposites

被引:40
作者
Basuki, Sri Wahyuni [1 ]
Schneider, Viktor [1 ]
Strunskus, Thomas [1 ]
Elbahri, Mady [2 ,3 ]
Faupel, Franz [1 ]
机构
[1] Univ Kiel, Tech Fak, Lehrstuhl Mat Verbunde, D-24143 Kiel, Germany
[2] Univ Kiel, Tech Fak, Nanochem & Nanoengn, D-24143 Kiel, Germany
[3] Helmholtz Zentrum Geesthacht, Zentrum Mat & Kustenforsch GmbH, Inst Polymerforsch, D-21502 Geesthacht, Germany
关键词
photoswitching conductance switching; carbon nanotube; polymer; nanocomposite; azobenzene; CARBON; COMPOSITES; DIARYLETHENES; MOLECULES; GOLD;
D O I
10.1021/acsami.5b01319
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We report on reversible light-controlled conductance switching in devices consisting of multiwalled carbon nanotube (MWCNT)-polymer nano-composites blended with azobenzene molecules and photoisomerization of the latter. Both the azobenene molecules and MWCNT, which are functionalized with carboxyl groups (MWCNT-COOH), are embedded independently in a poly(methyl methacrylate) matrix, and thin films are prepared by using a simple spin-coating technique. We demonstrate the feasibility of the present concept with a photocurrent switching amplitude of almost 10%.
引用
收藏
页码:11257 / 11262
页数:6
相关论文
共 41 条
[1]   Conductance switching in diarylethenes bridging carbon nanotubes [J].
Ashraf, M. K. ;
Bruque, Nicolas A. ;
Tan, Jeremy L. ;
Beran, Gregory J. O. ;
Lake, Roger K. .
JOURNAL OF CHEMICAL PHYSICS, 2011, 134 (02)
[2]   A review and analysis of electrical percolation in carbon nanotube polymer composites [J].
Bauhofer, Wolfgang ;
Kovacs, Josef Z. .
COMPOSITES SCIENCE AND TECHNOLOGY, 2009, 69 (10) :1486-1498
[3]   Light Switching of Molecules on Surfaces [J].
Browne, Wesley R. ;
Feringa, Ben L. .
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 2009, 60 :407-428
[4]   Molecular photodesorption from single-walled carbon nanotubes [J].
Chen, RJ ;
Franklin, NR ;
Kong, J ;
Cao, J ;
Tombler, TW ;
Zhang, YG ;
Dai, HJ .
APPLIED PHYSICS LETTERS, 2001, 79 (14) :2258-2260
[5]   Photoresponsive conductance switching of multi-walled carbon nanotubes bearing covalently linked spironaphthoxazine [J].
Cheong, In Woo ;
Wang, Sheng ;
Ki, Ho Seung ;
Kim, Sung-Hoon .
CURRENT APPLIED PHYSICS, 2009, 9 (06) :1269-1271
[6]   Multiwall carbon nanotube gas sensor fabricated using thermomechanical structure [J].
Cho, WS ;
Moon, SI ;
Lee, YD ;
Lee, YH ;
Park, JH ;
Ju, BK .
IEEE ELECTRON DEVICE LETTERS, 2005, 26 (07) :498-500
[7]   Extreme oxygen sensitivity of electronic properties of carbon nanotubes [J].
Collins, PG ;
Bradley, K ;
Ishigami, M ;
Zettl, A .
SCIENCE, 2000, 287 (5459) :1801-1804
[8]   Tuning the conductance of a molecular switch [J].
Del Valle, Miriam ;
Gutierrez, Rafael ;
Tejedor, Carlos ;
Cuniberti, Gianaurelio .
NATURE NANOTECHNOLOGY, 2007, 2 (03) :176-179
[9]   One-way optoelectronic switching of photochromic molecules on gold [J].
Dulic, D ;
van der Molen, SJ ;
Kudernac, T ;
Jonkman, HT ;
de Jong, JJD ;
Bowden, TN ;
van Esch, J ;
Feringa, BL ;
van Wees, BJ .
PHYSICAL REVIEW LETTERS, 2003, 91 (20)
[10]   A light-driven reversible conductance switch based on a few-walled carbon nanotube/azobenzene hybrid linked by a flexible spacer [J].
Feng, Yiyu ;
Zhang, Xuequan ;
Ding, Xuesong ;
Feng, Wei .
CARBON, 2010, 48 (11) :3091-3096