Process optimization for production of biodiesel from hazelnut oil, sunflower oil and their hybrid feedstock

被引:68
作者
Saydut, Abdurrahman [1 ]
Erdogan, Sait [2 ]
Kafadar, Aylin Beycar [2 ]
Kaya, Canan [2 ]
Aydin, Firat [2 ]
Hamamci, Candan [2 ]
机构
[1] Dicle Univ, Fac Engn, Min Engn Dept, TR-21280 Diyarbakir, Turkey
[2] Dicle Univ, Fac Sci, Dept Chem, TR-21280 Diyarbakir, Turkey
关键词
Biodiesel; Hybrid feedstock; Transesterification; Hazelnut (Corylus avellana L.) kernel oil; Sunflower (Helianthus annuus L.) oil; L. SEED OIL; RENEWABLE ENERGY-SOURCES; CORYLUS-AVELLANA L; METHYL-ESTER; TRANSESTERIFICATION; DIESEL; FUEL; PERFORMANCE; TURKEY;
D O I
10.1016/j.fuel.2016.06.114
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The most important constituent needed for biodiesel development is the feedstock. As the availability of feedstock is limited, the possibility of using the hybrid feedstock has been explored. Biodiesel has been synthesized from hazelnut (Corylus avellana L.) kernel oil, sunflower (Helianthus annuus L.) oil and hybrid (hazelnut and sunflower) (50: 50 v/v) feedstocks. Ester yield of vegetable oil to fatty acid methyl esters (FAME) was found to be 97.5%, 97.3% and 97.9% for hazelnut, sunflower and hybrid feedstocks respectively. The reaction parameters were used to be 6: 1 (methanol to oil) molar ratio, KOH (0.7%), at 60 +/- 0.5 degrees C for 2 h during alkali esterification for the three feedstocks. High yield from hybrid feedstock during transesterification reaction clearly indicated that the reaction was not selective for any particular oil. The obtained results important in that in case of scarcity of feedstock both oils could be mixed as well to maintain the constant supply of the feedstock in the perspective of industrial production of biodiesel. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:512 / 517
页数:6
相关论文
共 51 条
[1]   Alum as a heterogeneous catalyst for the transesterification of palm oil [J].
Aderemi, Benjamin O. ;
Hameed, B. H. .
APPLIED CATALYSIS A-GENERAL, 2009, 370 (1-2) :54-58
[2]  
Akinsiku AA, 2013, INT J SCI ENG RES, V4, P654
[3]   The potential of using vegetable oil fuels as fuel for diesel engines [J].
Altin, R ;
Çetinkaya, S ;
Yücesu, HS .
ENERGY CONVERSION AND MANAGEMENT, 2001, 42 (05) :529-538
[4]   Optimisation of biodiesel production by sunflower oil transesterification [J].
Antolín, G ;
Tinaut, FV ;
Briceño, Y ;
Castaño, V ;
Pérez, C ;
Ramírez, AI .
BIORESOURCE TECHNOLOGY, 2002, 83 (02) :111-114
[5]   The Basic Properties of Transesterified Corn Oil and Biodiesel-Diesel Blends [J].
Aydin, F. ;
Kafadar, A. B. ;
Erdogan, S. ;
Saydut, A. ;
Kaya, C. ;
Hamamci, C. .
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2011, 33 (08) :745-751
[6]   Pistacia terebintus L. Seed Oil: A New Possible Source of Biodiesel [J].
Baysal, Z. ;
Uyar, F. ;
Saydut, A. ;
Kaya, C. ;
Kafadar, A. B. ;
Hamamci, C. .
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2014, 36 (16) :1827-1834
[7]   Biodiesel production from renewable feedstocks: Status and opportunities [J].
Borugadda, Venu Babu ;
Goud, Vaibhav V. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2012, 16 (07) :4763-4784
[8]   Optimization of the reaction parameters for fast pseudo single-phase transesterification of sunflower oil [J].
Casas, Abraham ;
Maria Fernandez, Carmen ;
Jesus Ramos, Maria ;
Perez, Angel ;
Francisco Rodriguez, Juan .
FUEL, 2010, 89 (03) :650-658
[9]   Simultaneous Determination of Transition Metals in Hazelnuts (Corylus avellana L.) by ICP-OES [J].
Celik, K. Serdar ;
Aydin, Firat ;
Duz, M. Zahir ;
Aydin, Isil ;
Erdogan, Sait ;
Akba, Osman ;
Hamamci, Candan .
ATOMIC SPECTROSCOPY, 2014, 35 (05) :200-204
[10]   Variation of performance and emission characteristics of a diesel engine fueled with diesel, rapeseed oil and hazelnut oil methyl ester blends [J].
Celikten, Ismet ;
Mutlu, Emre ;
Solmaz, Hamit .
RENEWABLE ENERGY, 2012, 48 :122-126