Synthesis, structure, and luminescence properties of complex ZnLCl2 (L is 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline)

被引：4

作者：

Savel'eva, Z. A. ^{[1
]}

Popov, S. A. ^{[2
]}

Klevtsova, R. F. ^{[1
]}

Glinskaya, L. A. ^{[1
]}

Uskov, E. M. ^{[1
]}

Tkachev, A. V. ^{[2
]}

Larionova, S. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 09期

关键词：

zinc(II) complex; synthesis; X-ray diffraction analysis; luminescence;

D O I：

10.1007/s11172-009-0250-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A complex ZnLCl2 (L is 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline) was synthesized. According to X-ray diffraction data, the Zn2+ ions in mononuclear molecules of the obtained complex coordinate two N atoms of the bidentate chelating ligand L and two Cl atoms. The coordination polyhedron Cl2N2 represents a distorted tetrahedron. In solid state at 300 K, the ligand L exhibits weak photoluminescence in the visible spectral range. The complex ZnLCl2 exhibits bright blue photoluminescence.

引用

页码：1837 / 1840

页数：4

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