Piezoelectric and ferroelectric properties of new Pb9Ce2Ti12O36 and lead-free Ba2NdTi2Nb3O15 ceramics

被引:3
作者
Burianova, Lidmila [1 ,2 ]
Panos, Stanislav [1 ,2 ]
Stennett, Martin C. [3 ]
West, Anthony R. [3 ]
Subodh, Ganesanpotti [4 ]
Sebastian, Mailadil T. [4 ]
Kamba, Stanislav [5 ]
机构
[1] Tech Univ Liberec, Dept Phys, Liberec 46117, Czech Republic
[2] Tech Univ Liberec, Int Ctr Piezoelect Res, Liberec 46117, Czech Republic
[3] Univ Sheffield, Dept Mat Engn, Sheffield S1 3JD, S Yorkshire, England
[4] Natl Inst Interdisciplinary Sci & Technol, Mat & Minerals Div, Trivandrum 695019, Kerala, India
[5] Acad Sci Czech Republic, Inst Phys, Prague 18221 8, Czech Republic
基金
英国工程与自然科学研究理事会;
关键词
Ferroelectric properties; Piezoelectric properties; Pb9Ce2Ti12O36; Pb free ferroelectric ceramics; SYSTEM;
D O I
10.1007/s10832-010-9598-3
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this paper, measurements of the nonlinear ferroelectric, piezoelectric and dielectric properties of Pb9Ce2Ti12O36 (Pb9CTO) and Ba2NdTi2Nb3O15 (BNTN) ferroelectric ceramics are presented. Hysteresis P(E) loops were measured as a function of applied electric field, frequency and temperature. The coercive field (E (c)) and remnant polarization (P (r)) displayed temperature and frequency dependence. Lead-free BNTN ceramics exhibited a coercive field E (c) > 2.4 kV mm(-1) and a piezoelectric coefficient d (33) = 2 pC N-1. The hysteresis loop was pinched above 110A degrees C and a linear response was observed at 155A degrees C, typical of a paraelectric material. Pb9CTO was shown to be ferroelectric with coercive field E (c) = 1.2 kV mm(-1) and a d (33) = 65 pC N-1. The frequency dependences of the impedance of the Pb9CTO discs were analyzed.
引用
收藏
页码:116 / 121
页数:6
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