Ionic liquid directed construction of foam-like mesoporous boron-doped graphitic carbon nitride electrode for high-performance supercapacitor

被引:32
|
作者
Kong, Lirong [1 ,2 ]
Chen, Quanrun [1 ]
Shen, Xiaoping [1 ]
Zhu, Guoxing [1 ]
Zhu, Jun [1 ]
机构
[1] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China
[2] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Peoples R China
基金
中国博士后科学基金;
关键词
Boron doping; Graphitic carbon nitride; Hierarchical; Ionic liquid; Supercapacitor; HIGH VOLUMETRIC PERFORMANCE; HIGH-SURFACE-AREA; POROUS CARBON; GRAPHENE; CO; ELECTROCATALYST; CAPACITANCE; SITES;
D O I
10.1016/j.jcis.2018.07.135
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Carbon materials with controllable hierarchically porous structure and high doping level are expect to exhibit superior energy storage performance when used as electrode materials for supercapacitors. Herein, we report the preparation of a novel foam-like boron-doped carbon nitride material with hierarchically porous structure and high doping contents of nitrogen (21.45 +/- 0.93 at%) and boron (6.46 +/- 0.60 at%). Due to the unique compositional and structural features, this material exhibits high energy storage performance, including a large specific capacitance of similar to 660.6 F g(-1) at 0.1 A g(-1) and a high capacitance retention after 10,000 cycles. This study can provide new ideas for the development of carbon based electrode materials with unique hierarchically porous structure and improved doping level. (C) 2018 Elsevier Inc. All rights reserved.
引用
收藏
页码:261 / 271
页数:11
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