APPLICATION OF A NEW 4′-FUNCTIONALIZED 2,2′: 6′,2".TERPYRIDINE RUTHENIUM(II) COMPLEX AS A SENSITIZER IN DYE SENSITIZED SOLAR CELLS

被引：0
|
作者：
Nasirian, Azam [1 ]
Mirkhani, Valiollah [1 ]
Moghadam, Majid [1 ]
Tangestaninejad, Shahram [1 ]
Mohammadpoor-Baltork, Iraj [1 ]
机构：
[1] Univ Isfahan, Dept Chem, Catalysis Div, Esfahan 8174673441, Iran
来源：
HETEROCYCLES | 2021年 / 102卷 / 09期
关键词：
METAL-COMPLEXES; TIO2; TERPYRIDINE; MACROMOLECULES; NANOPARTICLES; ADSORPTION; EFFICIENCY; SURFACES; LIGANDS;
D O I：
10.3987/COM-21-14454
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In this work, the synthesis of a Ru(II) complex derived from 4'.functionalized 2,2':6', 2''.terpyridine ligand was described and the its spectral property of this complex was investigated. We synthesized this ligand and used that for the synthesis of Ru(II) complex. Ligand and complex were characterized by UV-vis, FT.IR, ESI-MS, CHN analysis and NMR methods. After synthesis and characterization of this complex, we investigated the application of this complex as a photosensitizer in manufacturing of dye-sensitized solar cells. A sandwich cell was prepared using the dye anchored TiO2 film as a working electrode and a second conducting glass coated with chemically deposited platinum as a counter electrode. The application of this complex in a dye-sensitized nanocrystalline TiO2 solar cell has demonstrated a short-circuit current density of 12.84 mA, with an open circuit potential of 0.69 V. The total efficiency of this dye-sensitized solar cell with this complex was 4.97%.
引用
收藏
页码：1767 / 1778
页数：12
相关论文
共 50 条
  • [31] Ruthenium Sensitizers with 2,2′-Bipyrimidine or a 5,5′-Disubstituted 2,2′-Bipyrimidine Ligand: Synthesis, Photo- and Electrochemical Properties, and Application to Dye-Sensitized Solar Cells
    Ozawa, Hironobu
    Kawaguchi, Hiroki
    Okuyama, Yu
    Arakawa, Hironori
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 2013 (29) : 5187 - 5195
  • [32] Crystal structure, thermal and luminescent properties of the complex of zinc(II) acrylate and 4′-phenyl-2,2′:6′,2"-terpyridine
    Baimuratova, Rose K.
    Sorin, Evgeny S.
    Korchagin, Denis, V
    Gutsev, Lavrenty G.
    Shilov, Gennadii, V
    Zhinzhilo, Vladimir A.
    Uflyand, Igor E.
    Akkuratov, Alexander, V
    Dzhardimalieva, Gulzhian I.
    INORGANICA CHIMICA ACTA, 2025, 581
  • [33] Synthesis of benzimidazole moiety heteroleptic ruthenium complex and use as sensitizer in dye-sensitized solar cells
    Orhan, Ersin
    Gokcen, Muharrem
    Taran, Songul
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2021, 127 (12):
  • [34] Synthesis, crystal structure and magnetic property of a Ni(II) complex with 4′-(4-methoxyphenyl)-2,2′:6′,2"-terpyridine
    Fu, Wei-Wei
    Shen, Jing-Run
    Tang, Zi-Qing
    Peng, Yong-Qiong
    Yi, Qing
    INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (12) : 1664 - 1667
  • [35] Effect of solvent on the crystal structures of copper(II) complexes based on 4′-(4-methoxyphenyl)-2,2′:6′,2"-terpyridine and 4′-(3-chlorophenyl)-2,2′:6′,2"-terpyridine
    Fu, W. W.
    Cheng, Q. W.
    Wang, H. Y.
    He, F. Z. R.
    Liu, Y.
    Zhang, F. X.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2017, 43 (08) : 547 - 558
  • [36] Functionalization of Multi-Walled Carbon Nanotubes with Bis(2,2′:6′,2"-Terpyridine) Ruthenium(II)-Connected Diblock Polymer
    Li, Huayang
    Wu, Jie
    Ingram, Conrad W.
    Harruna, Issifu I.
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2012, 12 (05) : 3739 - 3750
  • [37] Synthesis of ruthenium complex and its application in dye-sensitized solar cells
    Song, Hye-Kyung
    Park, Young Ho
    Han, Chi-Hwan
    Jee, Jong-Gi
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2009, 15 (01) : 62 - 65
  • [38] A new terpyridine cobalt complex redox shuttle for dye-sensitized solar cells
    Salvatori, Paolo
    Marotta, Gabriele
    Cinti, Antonio
    Mosconi, Edoardo
    Panigrahi, Mallika
    Giribabu, Lingamallu
    Nazeeruddin, Mohammad K.
    De Angelis, Filippo
    INORGANICA CHIMICA ACTA, 2013, 406 : 106 - 112
  • [39] 4,4′,5,5′-Tetracarboxy-2,2′-bipyridine Ru(II) Sensitizers for Dye-Sensitized Solar Cells
    Chou, Chun-Cheng
    Hu, Fa-Chun
    Wu, Kuan-Lin
    Duan, Tainan
    Chi, Yun
    Liu, Shih-Hung
    Lee, Gene-Hsiang
    Chou, Pi-Tai
    INORGANIC CHEMISTRY, 2014, 53 (16) : 8593 - 8599
  • [40] [Fe(4′-PhStpy)2][PF6]2 (4′-PhStpy=4′-phenylthio-2,2′:6′,2"-terpyridine): A centrosymmetric embrace
    Tao, Yaqiu
    Constable, Edwin C.
    Housecroft, Catherine E.
    Neuburger, Markus
    INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 20 : 180 - 183
12345