Solvent-free cyanosilylation of aldehydes catalyzed by SMI2

被引：13
作者：
George, Soney C. [1 ]
Kim, Sung Soo [1 ]
Kadam, Santosh T. [1 ]
机构：
[1] Inha Univ, Dept Chem, Inchon 402751, South Korea
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2007年 / 21卷 / 11期
基金：
美国安德鲁·梅隆基金会; 美国食品与农业研究所;
关键词：
cyanohydrins; aldehydes; solvent-free; SmI2;
D O I：
10.1002/aoc.1324
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A novel method to obtain racemic cyanohydrin silylethers by reaction of trimethylsilyl cyanide with a variety of aldehydes promoted by catalysis of SmI2 is reported. The corresponding cyanosilylethers were obtained in high yields (up to 99%) in solvent- free conditions at room temperature within a relatively short time using 0.01-0.5 mol% catalyst loadings. Copyright (c) 2007 John Wiley & Sons, Ltd.
引用
收藏
页码：994 / 998
页数：5
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