Oxygen K-edge near edge X-ray absorption fine structures of O and OH overlayers on Pt(111)

被引：9
|
作者：
Nagasaka, M
Nakai, I
Kondoh, H
Ohta, T
Carravetta, V
机构：
[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
[2] CNR, Ist Proc Chim Fis, Area Ric, I-56124 Pisa, Italy
来源：
CHEMICAL PHYSICS LETTERS | 2003年 / 375卷 / 3-4期
关键词：
D O I：
10.1016/S0009-2614(03)00876-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
O K-edge near edge X-ray absorption fine structure (NEXAFS) spectra of atomic 0 and OH adsorbates on Pt(I 1 1) were measured and interpreted by theoretical calculations based on the multiple scattering and molecular orbital methods. Comparison of the observed and calculated spectra from OH/Pt(l 1 1) confirmed that the OH species adsorb on the atop site with the O-H bond tilted from the surface normal. The spectra from O/Pt(l 1 1) were well reproduced by the structural model proposed by the previous LEED analysis that 0 is located at the hollow site with 1.19 Angstrom above the Pt top layer. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：419 / 424
页数：6
相关论文
共 50 条
  • [21] Hydrogen bonding in acetone clusters probed by near-edge x-ray absorption fine structure spectroscopy in the carbon and oxygen K-edge regions
    Tamenori, Y.
    Takahashi, O.
    Yamashita, K.
    Yamaguchi, T.
    Okada, K.
    Tabayashi, K.
    Gejo, T.
    Honma, K.
    JOURNAL OF CHEMICAL PHYSICS, 2009, 131 (17):
  • [22] Characterization of coke deposited on catalysts by carbon K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy
    Hiromichi Shimada
    Motoyasu Imamura
    Nobuyuki Matsubayashi
    Takeru Saito
    Tomoaki Tanaka
    Takashi Hayakawa
    Shigeo Kure
    Topics in Catalysis, 2000, 10 : 265 - 271
  • [23] An X-ray absorption near edge spectroscopy (XANES) study on organochromium complexes at the Cr K-edge
    Engemann, C
    Hormes, J
    Longen, A
    Dotz, KH
    CHEMICAL PHYSICS, 1998, 237 (03) : 471 - 481
  • [24] Ionic nature of Ge(II)-centered dications: a germanium K-edge X-ray absorption near edge structures study
    Ward, Matthew J.
    Rupar, Paul A.
    Murphy, Michael W.
    Yiu, Yun-Mui
    Baines, Kim M.
    Sham, T. K.
    CHEMICAL COMMUNICATIONS, 2010, 46 (37) : 7016 - 7018
  • [25] K-EDGE AND L-EDGE X-RAY ABSORPTION STUDIES OF NITROGENASE
    CHEN, J
    GEORGE, SJ
    CHRISTIANSEN, J
    VANELP, J
    WANG, X
    CRAMER, SP
    TITTSWORTH, R
    HALES, B
    FASEB JOURNAL, 1992, 6 (01): : A314 - A314
  • [26] A new spectroelectrochemical cell for in situ measurement of Pt and Au K-edge X-ray absorption fine structure
    Kaito, Takahiro
    Mitsumoto, Hisashi
    Sugawara, Seiho
    Shinohara, Kazuhiko
    Uehara, Hiromitsu
    Ariga, Hiroko
    Takakusagi, Satoru
    Asakura, Kiyotaka
    REVIEW OF SCIENTIFIC INSTRUMENTS, 2014, 85 (08):
  • [27] PHOTOACOUSTIC X-RAY ABSORPTION FINE-STRUCTURE SPECTROSCOPY OF THE NI K-EDGE
    REICHLING, M
    MASUJIMA, T
    SHIWAKU, H
    KAWATA, H
    ANDO, M
    MATTHIAS, E
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1989, 49 (06): : 707 - 710
  • [28] X-ray absorption near edge structures of DNA or its components around the oxygen K-shell edge
    Akamatsu, K
    Yokoya, A
    RADIATION RESEARCH, 2001, 155 (03) : 449 - 452
  • [29] X-ray absorption coefficient of rubidium in the K-edge region
    Preseren, R
    Kodre, A
    RADIATION PHYSICS AND CHEMISTRY, 1999, 55 (04) : 363 - 366
  • [30] Oxygen K-edge X-ray absorption fine structure studies of vacuum-deposited ice films
    Zubavichus, Yan
    Zharnikov, Michael
    Yang, Yong-Jie
    Fuchs, Oliver
    Umbach, Eberhard
    Heske, Clemens
    Grunze, Michael
    LANGMUIR, 2006, 22 (17) : 7241 - 7247
12345