A comparison of the benzylic and the allylic group as a donor in the formal [4+2] cycloaddition to tetrahydropyrans using donor-acceptor cyclobutanes

被引：5

作者：

Ahmed, Awais ^{[1
]}

Christie, Steven D. R. ^{[1
]}

Pritchard, Gareth J. ^{[1
]}

机构：

[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England

来源：

TETRAHEDRON LETTERS | 2017年 / 58卷 / 31期

关键词：

Cyclobutanes; Tetrahydropyrans; Cycloaddition; Lewis acids; BIOMIMETIC SYNTHESIS; ALDEHYDES; 3-ETHOXYCYCLOBUTANONES; KETONES; PYRIDOMACROLIDIN; PHENANTHRIDINES; REARRANGEMENT; PALLADIUM; ROUTES;

D O I：

10.1016/j.tetlet.2017.06.046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The allyl group was shown to be preferred over the benzyl group as a donor in the formal [4+2]-cyclo-addition reaction between a donor-acceptor cyclobutane and various aldehydes to give tetrahydropyrans. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：3028 / 3031

页数：4

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