Modelling of CO2 capture and separation from different gas mixtures using semiclathrate hydrates

被引：1
作者：
Amin, J. Sayyad [1 ]
Bahadori, M. [2 ,3 ]
Bahadori, A. [3 ]
Souraki, B. Abbasi [1 ]
Rafiee, S. [1 ]
机构：
[1] Univ Guilan, Dept Chem Engn, Rasht, Iran
[2] Natl Iranian Drilling Co, Dept Waste Management, Tehran, Iran
[3] So Cross Univ, Sch Environm Sci & Engn, Lismore, NSW 2480, Australia
来源：
PETROLEUM SCIENCE AND TECHNOLOGY | 2016年 / 34卷 / 05期
关键词：
CO2; separation; promoters; hydrate; Vandermonde matrix; genetic algorithm; PHASE-EQUILIBRIUM MEASUREMENTS; AQUEOUS-SOLUTION SYSTEMS; CARBON-DIOXIDE; LANDFILL GAS; BROMIDE; PREDICTION;
D O I：
10.1080/10916466.2015.1132235
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
In this work we present a model for predicting hydrate formation condition to separate carbon dioxide (CO2) from different gas mixtures such as fuel gas (H-2+CO2), flue gas (N-2+CO2), and biogas gas (CH4+CO2) in the presence of different promoters such as tetra-n-butylammonium bromide (TBAB), tetra-n-butylammonium chloride (TBAC), tetra-n-butylammonium fluoride (TBAF), tetra-n-butyl ammonium nitrate (TBANO(3)), and tetra-n-butylphosphonium bromide (TBPB). The proposed method was optimized by genetic algorithm. In the proposed model, hydrate formation pressure is a function of temperature and a new variable in term of Z, which used to cover different concentrations of studied systems. The study shows experimental data and predicted values are in acceptable agreement.
引用
收藏
页码：406 / 414
页数：9
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