Lewis Acid-Catalyzed [3+3] Annulation of Donor-Acceptor Cyclopropanes and Indonyl Alcohols: One Step Synthesis of Substituted Carbazoles with Promising Photophysical Properties

被引：34

作者：

Varshnaya, Rohit Kumar ^{[1
]}

Banerjee, Prabal ^{[1
]}

机构：

[1] Indian Inst Technol Ropar, Dept Chem, Nangal Rd, Rupnagar 140001, Punjab, India

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 84卷 / 03期

关键词：

DIASTEREOSELECTIVE SYNTHESIS; CYCLOADDITION REACTIONS; ALKALOIDS; INDOLES; CONSTRUCTION; DERIVATIVES; CYCLIZATION; REACTIVITY; ANALOGS;

D O I：

10.1021/acs.joc.8b02733

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly efficient protocol to access carbazole from donor acceptor cyclopropane and indonyl alcohol via [3+3] annulation in the presence of a Lewis acid has been demonstrated. This method facilitates the post functionalization of the substituted carbazole into a fully conjugated pi-system exhibiting intense emission bands in the visible range of the spectrum and also offers a convenient route toward the synthesis of pityriazole derivatives.

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收藏

页码：1614 / 1623

页数：10

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